36094-19-6Relevant academic research and scientific papers
THERMAL REACTIONS OF BENZOSILACYCLOBUTENES WITH ALCOHOLS
Kang, Kyung-Tae,Seo, Hee-Chan,Kim, Kwang-Nam
, p. 4761 - 4762 (2007/10/02)
In the thermal reaction with alcohols, benzosilacyclobutenes underwent both benzylsilicon and aryl-silicon bond rupture to yield (dialkyl)alkoxy-o-tolylsilanes and (dialkyl)-alkoxybenzylsilanes, respectively.
MARKED MEDIUM EFFECTS ON THE SUBSTITUTION AND THE ADDITION-REARRANGEMENT-EJECTION REACTIONS OF (HALOMETHYL)SILANES WITH METHOXIDES
Kreeger, R. L.,Menard, P. R.,Sans, E. A.,Shechter, H.
, p. 1115 - 1118 (2007/10/02)
Reactions of methoxides with (halomethyl)silanes at silicon are facilitated by aprotic solvents and cation separation.
Some Methoxysilanes, Disiloxanes and Digermoxanes with Effectiveness of Odour. Sila-Substituted Perfumes, III.
Wrobel, Dieter,Wannagat, Ulrich,Harder, Ulrich
, p. 381 - 388 (2007/10/02)
The odour of the formerly unknown compounds benzyldimethylmethoxysilane 2a (flower-honey like with a minty component; intensity middle), bis(benzyl)tetramethyldisiloxane 4a (flowerlike; very weak) and bis(benzyl)tetramethyldigermoxane 9 (almond-soapy like; relatively strong) was registered and compared with related compounds (for example benzyldimethylmethoxymethane 5a, camphor-radish like).Information is given on preparation and analytical and structural investigation of several methoxysilanes and disioxanes with benzyl and phenethyl groups (compare equations and experimental part). - Keywords: Digermoxanes; Disiloxanes; Methoxysilanes; Odour; Sila-perfumes
SUBSTITUENT EFFECTS OF SOME ORGANOSILYLMETHYL GROUPS
Eaborn, Colin,Hancock, Alan R.,Stanczyk, Wlodzimierz A.
, p. 147 - 154 (2007/10/02)
The charge transfer frequencies for some tetracyanoethylene-PhX complexes have been used to derive ?+p constants and 13C NMR data to derive ?0R constants for the X groups, with the following results (X, -?+
