36103-68-1Relevant academic research and scientific papers
Tertiary phosphine complexes of rhodium(I) and rhodium(III) chlorides
Intille
, p. 695 - 702 (1972)
The most complete series of tertiary phosphine complexes of rhodium yet reported has been prepared. Depending on the particular phosphine and the method of preparation, several different types of complexes may be formed. These include RhCl3(PR
Regioselectivity in the rhodium catalysed 1,4-hydrosilylation of isoprene. Aspects on reaction conditions and ligands
Gustafsson, Magnus,Frejd, Torbj?rn
, p. 438 - 443 (2007/10/03)
The regioselectivity in the Rh catalysed 1,4-hydrosilylation of isoprene was investigated. Variation of solvents and temperature did not significantly affect the isomer distribution between tail-product (I) and head-product (II). The choice of ligands had
