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Benzophenone, 4-fluoro-, oxime is a chemical compound with the molecular formula C13H9FNO. It is a derivative of benzophenone, featuring a fluorine atom at the 4-position and an oxime group attached to the carbonyl carbon. This organic compound is characterized by its aromatic structure, with a benzene ring connected to a phenyl ketone group. The presence of the fluorine atom imparts unique electronic and steric properties, making it a valuable intermediate in the synthesis of various pharmaceuticals, agrochemicals, and other specialty chemicals. The oxime functionality further enhances its reactivity and potential applications in chemical transformations. Overall, Benzophenone, 4-fluoro-, oxime is a significant molecule in the realm of organic chemistry, offering a range of possibilities for further functionalization and development.

362-99-2

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362-99-2 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 362-99-2 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 3,6 and 2 respectively; the second part has 2 digits, 9 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 362-99:
(5*3)+(4*6)+(3*2)+(2*9)+(1*9)=72
72 % 10 = 2
So 362-99-2 is a valid CAS Registry Number.

362-99-2SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 14, 2017

Revision Date: Aug 14, 2017

1.Identification

1.1 GHS Product identifier

Product name (4-fluorophenyl)phenylmethanone oxime

1.2 Other means of identification

Product number -
Other names 4-fluoro-benzophenone-seqtrans-oxime

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:362-99-2 SDS

362-99-2Relevant academic research and scientific papers

Vilsmeier-Haack reagent mediated synthetic transformations with an immobilized iridium complex photoredox catalyst

Zhi, Peng,Xi, Zi-Wei,Wang, Dan-Yan,Wang, Wei,Liang, Xue-Zheng,Tao, Fei-Fei,Shen, Run-Pu,Shen, Yong-Miao

, p. 709 - 717 (2019)

An immobilized iridium complex photocatalyst Ir(ppy)2(PDVB-py) was synthesized by immobilization of the iridium complex onto the nanoporous vinylpyridine-divinylbenzene copolymer (PDVB-py). Its application for the synthesis of amides, nitriles, and anhydrides was reported via reactions under the action of the visible-light-driven in situ generated Vilsmeier-Haack reagent from CBr4 in DMF. The results showed that this heterogeneous photocatalyst has extremely high activity and excellent stability to be recycled five times.

Preparation method of ketoxime

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Paragraph 0038-0040, (2018/07/30)

The invention belongs to the technical field of ketoxime and specifically relates to a preparation method of ketoxime. The preparation method comprises the following steps: (1) sufficiently mixing ketone and hydroxylamine hydrochloride, adding absolute ethyl alcohol, and stirring till total dissolution to obtain mixed liquid 1; (2) adding imidazolyl anion functionalized ionic liquid into the mixedliquid 1, and heating till ethanol reflux, wherein reaction liquid is obtained after the reaction; (3) removing ethanol in the reaction liquid, adding deionized water and stirring to separate out solid, and performing suction filtration and washing to obtain white solid ketoxime. According to the preparation method provided by the invention, by taking the imidazolyl anion functionalized ionic liquid as a catalyst, a reaction between ketone and hydroxylamine hydrochloride can be efficiently catalyzed, and the preparation method has the advantages of mild reaction conditions, high product yieldand purity and the like.

Mercury-catalyzed rearrangement of ketoximes into amides and lactams in acetonitrile

Ramalingan, Chennan,Park, Yong-Tae

, p. 4536 - 4538 (2008/02/04)

(Chemical Equation Presented) An acetonitrile solution of mercury(II) chloride has been found to catalyze efficiently the conversion of a diverse range of ketoximes into their corresponding amides/lactams.

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