362-99-2Relevant articles and documents
Vilsmeier-Haack reagent mediated synthetic transformations with an immobilized iridium complex photoredox catalyst
Zhi, Peng,Xi, Zi-Wei,Wang, Dan-Yan,Wang, Wei,Liang, Xue-Zheng,Tao, Fei-Fei,Shen, Run-Pu,Shen, Yong-Miao
, p. 709 - 717 (2019)
An immobilized iridium complex photocatalyst Ir(ppy)2(PDVB-py) was synthesized by immobilization of the iridium complex onto the nanoporous vinylpyridine-divinylbenzene copolymer (PDVB-py). Its application for the synthesis of amides, nitriles, and anhydrides was reported via reactions under the action of the visible-light-driven in situ generated Vilsmeier-Haack reagent from CBr4 in DMF. The results showed that this heterogeneous photocatalyst has extremely high activity and excellent stability to be recycled five times.
Mercury-catalyzed rearrangement of ketoximes into amides and lactams in acetonitrile
Ramalingan, Chennan,Park, Yong-Tae
, p. 4536 - 4538 (2008/02/04)
(Chemical Equation Presented) An acetonitrile solution of mercury(II) chloride has been found to catalyze efficiently the conversion of a diverse range of ketoximes into their corresponding amides/lactams.