36217-89-7

Basic information

• Product Name: (1S,4S)-(N-benzyl)-(2-keto-7,7-dimethylbicyclo[2.2.1]hept-1-yl)methanesulfonamide
• Synonyms: (1S,4S)-(N-benzyl)-(2-keto-7,7-dimethylbicyclo[2.2.1]hept-1-yl)methanesulfonamide
• CAS NO: 36217-89-7
• Molecular Weight: 321.441
• Mol File: 36217-89-7.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: (1S,4S)-(N-benzyl)-(2-keto-7,7-dimethylbicyclo[2.2.1]hept-1-yl)methanesulfonamide(CAS DataBase Reference)
• NIST Chemistry Reference: (1S,4S)-(N-benzyl)-(2-keto-7,7-dimethylbicyclo[2.2.1]hept-1-yl)methanesulfonamide(36217-89-7)
• EPA Substance Registry System: (1S,4S)-(N-benzyl)-(2-keto-7,7-dimethylbicyclo[2.2.1]hept-1-yl)methanesulfonamide(36217-89-7)

Safety Data

• Hazardous Substances Data: 36217-89-7(Hazardous Substances Data)

Upstream product

• 21286-54-4 Camphorsulfonyl chloride 
• 100-46-9 benzylamine 
• 100-39-0 benzyl bromide 
• 60886-80-8 (1S)-(-)-camphorsulfonylimine 

Downstream Products

• 1239861-64-3 C₁₇H₂₃NO₂S₂ 
• 1442093-97-1 (1S,2R,4R)-N-benzyl-2-morpholino-7,7-dimethylbicyclo[2.2.1]hept-1-ylmethanesulfonamide 
• 1442093-94-8 (1S,2R,4R)-N-benzyl-2-amino-7,7-dimethylbicyclo[2.2.1]hept-1-ylmethanesulfonamide 
• 1037077-01-2 (E)-1-[N-benzyl-N-{(1S)-(+)-10-camphorsulfonyl}amino]-2-diphenylthiophosphinyl-1-phenylethene 
• 912365-40-3 (1S,12S)-N-benzyl-15,15-dimethyl-3-azatetracyclo[10.2.1.0(2,11).0(4,9)]pentadeca-2⁽¹¹⁾,3,5,7,9-pentaen-1-ylmethanesulfonamide 
• 912365-41-4 (1S,16S)-N-benzyl-19,19-dimethyl-3-azapentacyclo[14.2.1.0(4,13).0(5,10)]nonadeca-2⁽¹⁵⁾,3,5⁽¹⁰⁾,6,8,11,13-heptaen-1-ylmethanesulfonamide 

Relevant articles and documents

(CAMPHORYLSULFONYL)IMINE DIANION IN THE SYNTHESIS OF NEW OPTICALLY PURE (CAMPHORYLSULFONYL)OXAZIRIDINE DERIVATIVES

New, more efficient enantiomerically pure (camphorylsulfonyl)oxaziridines are prepared by mono alkylation of the dianion of (camphorylsulfonyl)imine at the carbon atom adjacent to the sulfonyl group.

A PROCESS FOR THE MANUFACTURE OF CHIRAL CATALYSTS AND THEIR SALTS

The present invention provides efficient and economical methods for synthesis of (-)-2-exo-morpholinoisoborne-10-thiol, its enantiomer, and related chiral catalysts. Novel compounds and methods of asymmetric synthesis are also disclosed.

Synthesis of camphorsulfonamide-based quinoline ligands and their N-oxides: first use in the enantioselective addition of organozinc reagents to aldehydes

The preparation of several camphorsulfonamide-based quinoline derivatives and their N-oxides was accomplished via an indirect Friedlaender synthesis using aminobenzylic alcohols and RuCl2(DMSO)4 as a catalyst. These ligands were tested in the enantioselective addition of dialkylzinc reagents to aldehydes, with enantiomeric excesses up to 96%. A similar protocol using triphenylborane and diethylzinc gave the corresponding phenylation process.