36304-20-8Relevant academic research and scientific papers
CuI promoted sulfenylation of organozinc reagents with arylsulfonyl chlorides
Fu, Ying,Su, Yuhu,Xu, Qin-Shan,Du, Zhengyin,Hu, Yulai,Wang, Ke-Hu,Huang, Danfeng
, p. 6018 - 6022 (2017)
A CuI promoted sulfenylation of organozinc reagents with arylsulfonyl chlorides/PPh3 has been explored. This reaction proceeded smoothly through an alkyl/aryl radical (generated from organometallics) under mild conditions and produced the desired sulfide products in excellent yields.
ION PAIR CATALYSIS OF TUNGSTATE AND MOLYBDATE
-
Page/Page column 35, (2017/10/30)
D The present invention relates to ion pair catalysts (I) comprising the cationic bisguanidinium ligand (A) and diperoxomolybdate anion (B). The present invention also relates to ion pair catalysts (III) comprising the cationic bisguanidinium ligand (C) and peroxotungstate anion (D). It further relates to the use of the said catalysts in the manufacture of enantiomerically enriched sulfoxides.
The reaction of grignard reagents with bunte salts: A thiol-free synthesis of sulfides
Reeves, Jonathan T.,Camara, Kaddy,Han, Zhengxu S.,Xu, Yibo,Lee, Heewon,Busacca, Carl A.,Senanayake, Chris H.
, p. 1196 - 1199 (2014/03/21)
S-Alkyl, S-aryl, and S-vinyl thiosulfate sodium salts (Bunte salts) react with Grignard reagents to give sulfides in good yields. The S-alkyl Bunte salts are prepared from odorless sodium thiosulfate by an SN2 reaction with alkyl halides. A Cu-
