36489-03-9

Usage

Chemical Properties

Clear colorless liquid

InChI:InChI=1/C4H11NS/c1-2-6-4-3-5/h2-5H2,1H3/p+1

Upstream product

• 151-56-4 ethyleneimine 
• 75-08-1 ethanethiol 
• 926-39-6 sulfuric acid mono-(2-amino-ethyl ester) 
• 74-96-4 ethyl bromide 
• 156-57-0 2-mercaptoethylamine hydrochloride 
• 75-03-6 ethyl iodide 
• 60-23-1 Cysteamine 

Downstream Products

• 89500-01-6 (3-thiapentyl)trimethylammonium iodide 
• 72290-13-2 4-[6-chloro-2-(2-ethylsulfanyl-ethylamino)-3-sulfamoyl-benzoyl]-morpholine 
• 101250-32-2 *,R^*)>-phenylmethyl 2-<<<1-<<<2-(ethylthio)ethyl>amino>carbonyl>-3-methylbutyl>thio>methyl>-1-pyrrolidinecarboxylate 
• 1203956-31-3 C₂₄H₂₆ClF₃N₄O₂S 
• 848491-59-8 N-(2-(diphenylphosphino)benzylidene)-2-(ethylthio)ethanamine 
• 1243258-02-7 3-(2-(ethylthio)ethylamino)-N-(3-ethynylphenyl)propanamide 
• 1243257-93-3 2-(2-(ethylthio)ethylamino)-N-(3-ethynylphenyl)acetamide 
• 1243258-12-9 4-(2-(ethylthio)ethylamino)-N-(3-ethynylphenyl)butanamide 
• 691363-49-2 4-(2-ethylsulfanyl-ethyl)amino-3-nitrobenzoic acid 

Relevant academic research and scientific papers

An approach to model the active site of peptidglycine-α-hydroxylating monooxygenase (PHM)

The copper(I) and copper(II) complexes [Cu((TMGet) 2NetSEt)]BPh4 (1·BPh4) and [Cu((TMGet)2NetSEt)Cl]Cl (2·Cl) with (TMGet)2NetSEt = ((Me2N) 2C=NCH2CH2)2NCH2CH 2SEt were synthesized and structurally characterized as a model system for the copper enzyme PHM, a monooxygenase involved in the activation of peptide hormones and neuropeptides. The reaction of the copper(I) complex 1·BPh4 with dioxygen has been studied using low temperature stopped-flow methods. However, in contrast to PHM no formation of an end-on copper superoxido complex could be observed. Instead an equilibrium between a bis-μ-oxo and a side-on peroxide complex was detected spectroscopically. Copyright

Thermoresponsive Sulfone and Sulfoxide-Containing Polyacrylamides

A series of thermoresponsive polyacrylamides containing sulfide, sulfone, or sulfoxide was successfully prepared by reversible addition-fragmentation chain transfer (RAFT) polymerization. The thermal properties of polyacrylamides with sulfone or sulfoxide, which have not been studied before, were investigated for the first time. While poly[N-(2-(propylsulfonyl)ethyl)acrylamide] (P2SO2) with sulfone groups was water insoluble, poly[N-(2-(propylsulfinyl)ethyl)acrylamide] (P2SO) with sulfoxide groups was water soluble, indicating that the sulfoxide moiety is more hydrophilic than sulfone. By controlling the end of the polymer chain, we synthesized poly[N-(2-(ethylsulfonyl)ethyl)acrylamide] (P1SO2) and poly[N-(2-(butylsulfinyl)ethyl)acrylamide] (P3SO), which exhibit an lower critical solution temperature (LCST) in water around 24–26°C. For adjusting a wide range of LCST, we synthesized the random copolymers by controlling the initial feed ratio of hydrophobic M2SO2 and hydrophilic M2SO. The amphiphilic block copolymers were also synthesized and assembled in water to yield the micelles. After adding H2O2 to this micellar solution, the hydrophobic block was oxidized and converted to a hydrophilic block, leading to the transformation of micelles to unimers.