36588-31-5Relevant academic research and scientific papers
Anionic cyclization of N -(trans -2,3-Diphenylaziridin-1-yl)imines: Its application to sesquiterpene synthesis via consecutive carbon-carbon bond-formation approach
Kim, Sunggak,Hwang, Jung-Il
, p. 1511 - 1514 (2010)
The anionic consecutive carbon-carbon (CC-C) bond formation can be achieved by the anionic cyclizations of N-(trans-2,3-diphenylaziridin-1-yl)imines with alkyllithiums. The synthetic efficiency of CC-C bond-formation approach has been demonstrated in the synthesis of dl-pentalenene and dl-cedrone. Georg Thieme Verlag Stuttgart New York.
Effects of substituent branching and chirality on the physical properties of ionic liquids based on cationic ruthenium sandwich complexes
Higashi, Tomomi,Ueda, Takahiro,Mochida, Tomoyuki
, p. 10041 - 10048 (2016/05/19)
An appropriate understanding of how substituents affect the physical properties of ionic liquids is important for the molecular design of ionic liquids. Toward this end, we investigated how the branching and chirality of substituents affect the physical p
Liquid crystalline N-aryl-β-aminovinyl ketones and their complexes with lanthanides
Turanova,Galyametdinov
, p. 1095 - 1099 (2008/02/05)
Liquid crystalline lanthanide complexes with N-aryl-substituted β-aminovinyl ketones were synthesized for the first time. The complexes give rise to smectic A mesophase and are stable only in the solid state; in going to solution, they dissociate with for
Anionic reactions of N-(trans-2,3-diphenylaziridin-1-yl)imines and their use as 1,1-dipoles in anionic cyclizations
Hwang, Jung-Il,Hong, Young-Taek,Kim, Sunggak
, p. 1513 - 1516 (2007/10/03)
Reaction of N-(trans-2,3-diphenylaziridin-1-yl)imines with alkyllithiums and organocuprates afforded the desired addition products after consecutive fragmentations along with liberation of stilbene and nitrogen gas, while the reaction of N-(2-phenylaziridin-1-yl)imines under similar conditions gave an anomalous by-product. Anionic cyclizations of N-(trans-2,3-diphenylaziridin-1- yl)imines using unactivated alkenes and alkynes as acceptors proceeded smoothly, yielding cyclized products in good yields.
