36629-09-1Relevant academic research and scientific papers
Synthesis and spectroscopic properties of linear oligoanilines
Rozalska,Kurylek,Franaszek,Kulszewicz-Bajer
, p. 105 - 114 (2004)
Two types of linear oligomers, namely Ph/NH2 and NH 2/NH2 end-capped oligoanilines have been synthesized by SNAr coupling/reduction sequence. The 1H NMR spectra of obtained compounds are strongly infl
Sandwich dimer complexes of zinc porphyrins bearing three-dimensionally oriented redox-active π-conjugated pendant groups
Hirao, Toshikazu,Saito, Kaori
, p. 415 - 418 (2002)
Treatment of the zinc porphyrins bearing four dimensionally oriented phenylenediamine strands with a bidentate ligand, DABCO, led to the formation of the sandwich dimer complexes, in which the porphyrin moieties are surrounded by π-conjugated pendant groups.
One-pot propagation of (Hetero)Arylamines: Modular synthesis of diverse Amino-di(hetero)arylamines
Liang, Xueting,Xu, Liang,Li, Cuihua,Jia, Xin,Wei, Yu
, p. 721 - 731 (2019/01/08)
Formal propagation of (hetero)arylamine is achieved via a one-pot Buchwald–Hartwig C–N cross-coupling and nitro reduction sequence, enabling a rapid modular synthesis of diverse amino-di(hetero)arylamines from (hetero)arylamines and halogenated nitrobenzenes. Various functionalized aromatic amines with different electronic and steric environments can be efficiently prolongated to formally incorporate another arylamino fragments. This approach has been successfully applied in the synthesis of more than forty amino-di(hetero)arylamines. The applicability of this method has also been demonstrated in the synthesis of oligoanilines and the tyrosine-kinase inhibitor Imatinib.
On the formation of mauvein: Mechanistic considerations and preparative results
Heichert, Christoph,Hartmann, Horst
experimental part, p. 747 - 755 (2009/12/26)
The reaction of aniline (AH2) with an oxidizing agent in acidic solution gives rise to the formation of a mixture of products containing, besides a variety of oligoanilines named as Aniline Black or Polyaniline, Mauvein as a deeply purple phena
Synthesis and spectroscopic properties of aniline tetramers. Comparative studies
Kulszewicz-Bajer, Irena,Rozalska, Izabela,Kurylek, Malgorzata
, p. 669 - 675 (2007/10/03)
A new synthetic method involving SNAr coupling of 4-fluoronitrobenzene to arylamines, followed by the reduction of the nitro groups, has been developed. Two types of aniline oligomers, namely Ph/NH 2 and NH2/NH2
