367-05-5

Basic information

• Product Name: Phenol, 2-fluoro-, sodium salt
• CAS NO: 367-05-5
• Molecular Formula: C6H5FO.Na
• Molecular Weight: 134.085
• Mol File: 367-05-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Phenol, 2-fluoro-, sodium salt(CAS DataBase Reference)
• NIST Chemistry Reference: Phenol, 2-fluoro-, sodium salt(367-05-5)
• EPA Substance Registry System: Phenol, 2-fluoro-, sodium salt(367-05-5)

Safety Data

• Hazardous Substances Data: 367-05-5(Hazardous Substances Data)

Upstream product

• 367-12-4 2-fluorophenol 

Downstream Products

• 80071-53-0 6-o-fluorophenoxy-4-thia-1-hexene 
• 363-52-0 3-fluorocatechol 
• 120-80-9 benzene-1,2-diol 
• 7446-81-3 sodium 2-propenoate 
• 69318-23-6 2-allyl-6-fluorophenol 
• 57264-49-0 1-(allyloxy)-2-fluorobenzene 
• 1580001-34-8 5-ethoxy-3-(4-chloro-2-(2-fluorophenoxy)benzyl)-4H-1,2,4-triazole 
• 1580001-31-5 2-amino-5-(4-chloro-2-(2-fluorophenoxybenzyl))-1,3,4-oxadiazole 
• 1580001-28-0 2-(4-chloro-2-(2-fluorophenoxy)phenyl)acetic acid hydrazide 
• 1580001-26-8 ethyl 2-(4-chloro-2-(2-fluorophenoxy)phenyl)acetate 
• 1580001-24-6 5-(4-chloro-2-(2-fluorophenoxy)benzyl)-3-benzylthio-4H-1,2,4-triazole 
• 1580001-23-5 5-(4-chloro-2-(2-fluorophenoxy)benzyl)-3-propylthio-4H-1,2,4-triazole 
• 1580001-22-4 5-(4-chloro-2-(2-fluorophenoxy)benzyl)-3-ethylthio-4H-1,2,4-triazole 
• 1273986-54-1 4?chloro?2?(2?fluorophenyloxy)benzoic acid 

Relevant articles and documents

Selective ortho-hydroxylation-defluorination of 2-fluorophenolates with a Bis(μ-oxo)dicopper(III) species

The bis(μ-oxo)dicopper(III) species [CuIII 2(μ-O)2(m-XYLMeAN)]2+ (1) promotes the electrophilic ortho-hydroxylation-defluorination of 2-fluorophenolates to give the corresponding catechols, a reaction that is not accomplishable with a (η2:η2-O2) dicopper(II) complex. Isotopic labeling studies show that the incoming oxygen atom originates from the bis(μ-oxo) unit. Ortho-hydroxylation-defluorination occurs selectively in intramolecular competition with other ortho-substituents such as chlorine or bromine. O in, F out: [CuIII2(μ-O) 2(m-XYLMeAN)]2+ is a bis(μ-oxo)dicopper(III) species and promotes the electrophilic ortho-hydroxylation-defluorination of 2-fluorophenolates to give the corresponding catechols. Isotopic labeling shows that the incoming oxygen atom originates from the bis(μ-oxo) unit. Ortho-hydroxylation-defluorination occurs selectively in intramolecular competition with other ortho-substituents such as chlorine or bromine.