36728-27-5Relevant academic research and scientific papers
Influence of the N-Sulphonyl and N-Alkyl Groups on Stereochemical Features of the Peroxy-acid-Imine Reaction
Bucciarelli, Maria,Forni, Arrigo,Moretti, Irene,Torre, Giovanni
, p. 923 - 926 (1983)
Asymmetric oxidation of prochiral sulphonylimines and N-alkylimines has been performed with several chiral peroxy-acids and under the same reaction conditions.The differences in the diastereoselectivity and in the enantioselectivity of the two reactions a
Oxidative deamination of various primary amines to the corresponding carbonyl compounds by using N-tert-butylphenylsulfinimidoyl chloride
Matsuo, Jun-Ichi,Kawana, Asahi,Fukuda, Yoshio,Mukaiyama, Teruaki
, p. 712 - 713 (2007/10/03)
Various linear and non-linear primary amines were oxidatively deaminated to afford the corresponding carbonyl compounds in good to excellent yields by the following procedure: (i) initial formation of their N-cyclohexylated or N-mesylated derivatives, (ii) subsequent oxidation of these derivatives by using N-tert-butylphenylsulfinimidoyl chloride (1) and DBU, (iii) one-pot acid-hydrolysis of thus formed imines to carbonyl compounds.
