36776-27-9

Basic information

• Product Name: Benzenethiol, 4-chloro-2-nitro-
• CAS NO: 36776-27-9
• Molecular Formula: C6H4ClNO2S
• Molecular Weight: 189.622
• Mol File: 36776-27-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzenethiol, 4-chloro-2-nitro-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenethiol, 4-chloro-2-nitro-(36776-27-9)
• EPA Substance Registry System: Benzenethiol, 4-chloro-2-nitro-(36776-27-9)

Safety Data

• Hazardous Substances Data: 36776-27-9(Hazardous Substances Data)

Upstream product

• 70-49-5 DL-thiomalic acid 
• 4153-06-4 4-chloro-2-nitrobenzenesulfenyl chloride 
• 50-99-7 D-glucose 
• 2050-66-0 bis(2-nitro-4-chlorophenyl)disulfide 
• 89-61-2 2,5-dichloronitrobenzene 
• 64-17-5 ethanol 
• 856977-04-3 1-(4-chloro-2-nitro-phenylsulfanyl)-2-methyl-propan-2-ol 
• 106-48-9 4-chloro-phenol 
• 89-64-5 p-chloro-o-nitrophenol 

Downstream Products

• 856977-04-3 1-(4-chloro-2-nitro-phenylsulfanyl)-2-methyl-propan-2-ol 
• 101423-14-7 6-chloro-2-phenacyl-4H-benzo[1,4]thiazin-3-one 
• 2050-66-0 bis(2-nitro-4-chlorophenyl)disulfide 
• 100542-79-8 (4-chloro-2-nitro-phenyl)-(4-methyl-benzyl)-sulfide 
• 1889-57-2 (4-chloro-2-nitrophenyl)(methyl)sulfane 
• 30067-02-8 (2S,3R)-3-(4-Chloro-2-nitro-phenylsulfanyl)-2-hydroxy-3-(4-methoxy-phenyl)-propionic acid methyl ester 
• 30067-02-8 (2R,3R)-3-(4-Chloro-2-nitro-phenylsulfanyl)-2-hydroxy-3-(4-methoxy-phenyl)-propionic acid methyl ester 
• 89938-32-9 (4-Chlor-2-nitro-phenylmercapto)-essigsaeure-amid 
• 30067-02-8 3-(4-Chloro-2-nitro-phenylsulfanyl)-2-hydroxy-3-(4-methoxy-phenyl)-propionic acid methyl ester 
• 96459-88-0 (4-chloro-2-nitro-phenyl)-(4-nitro-benzyl)-sulfide 
• 100638-12-8 ethyl 4-chloro-2-nitrophenylthio-α-phenylacetate 
• 1004-00-8 4-chloro-2-aminobenzenethiol 
• 2786-51-8 5-chlorobenzo[d]thiazole 
• 30253-28-2 3-(4-Chloro-2-nitro-phenylsulfanyl)-2-hydroxy-3-(4-methoxy-phenyl)-propionic acid 

Relevant articles and documents

Mitsunobu C-alkylation of β-alkoxycarbonyl 2-nitrobenzenesulfones and its use for the rapid synthesis of novel benzothiazine derivatives

Herein, we report the first examples of the Mitsunobu alkylation of β-alkoxycarbonyl 2-nitrobenzenesulfones. Wang resin was acylated with α-halocarboxylic acids followed by the reaction with 2-nitrothiophenols. After oxidation with m-chloroperbenzoic acid, the immobilized β-alkoxycarbonyl 2-nitrobenzensulfones were subjected to alkylation with various alcohols. The reaction outcome strongly depended on the selection of the alkylating species. After the reduction of the nitro group, acid-mediated cleavage and subsequent cyclization, the C2-(di)substituted benzothiazin-3(4H)-one 1,1-dioxides were obtained in high crude purities and good overall yields.

S-Aryl(tetramethyl)isothiouronium salts as potential antimicrobial agents, II

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