36898-58-5Relevant academic research and scientific papers
Metal-Free Synthesis of Aryl Selenocyanates and Selenaheterocycles with Elemental Selenium
Huang, Xiao-Bo,Liu, Miao-Chang,Wu, Hua-Yue,Zhang, Xue,Zhou, Yun-Bing
supporting information, p. 944 - 948 (2020/12/18)
This work reports a green method for the synthesis of aryl selenocyanates via a three-component reaction of arylboronic acids, Se powder, and trimethylsilyl cyanide (TMSCN) under metal-free and additive-free conditions. Remarkably, TMSCN acts as not only the substrate, but also the catalyst. Various selenaheterocycles can be also accessed with a catalytic amount of TMSCN.
Nature of Nonbonded Se...O Interactions Characterized by 17O NMR Spectroscopy and NBO and AIM Analyses
Iwaoka, Michio,Komatsu, Hiroto,Katsuda, Takayuki,Tomoda, Shuji
, p. 5309 - 5317 (2007/10/03)
To investigate the nature of nonbonded Se...O interactions, three series of 2-substituted benzeneselenenyl derivatives [2-(CHO)C6H 4SeX (1), 2-(CH2OH)C6H4SeX, (2), 2-(CH2OPr)C6H
