36954-50-4

Upstream product

• 106-49-0 p-toluidine 
• 698-16-8 benzohydroximoyl chloride 
• 147196-11-0 3-Phenyl-4-p-tolyl-1-oxa-2,4-diaza-spiro[4.6]undeca-2,6,8,10-tetraene 
• 622-32-2 (Z)-benzaldehyde oxime 
• 100-52-7 benzaldehyde 
• 932-90-1 Benzaldoxime 
• 932-90-1 syn-benzaldehyde oxime 
• 582-78-5 N-(4-methylphenyl)benzamide 
• 5373-55-7 N-(4-methylphenyl)thiobenzamide 

Downstream Products

• 111273-17-7 4-(4-methylphenyl)-3-phenyl-1,2,4-oxadiazol-5(4H)-one 
• 1018788-00-5 3,5-diphenyl-4-(4-methylphenyl)-4,5-dihydro-1,2,4,5-oxadiazaborole 
• 141693-79-0 4-(4-methylphenyl)-3-phenyl-1,2,4-oxadiazole-5(4H)-thione 
• 14016-00-3 6-methyl-2-phenylbenzoxazole 
• 1427216-61-2 C₇₄H₁₂N₂ 
• 2963-65-7 5-methyl-2-phenyl-1H-1,3-benzimidazole 
• 141693-81-4 3-phenyl-4-(p-tolyl)-1,2,4-thiadiazole-5(4H)-thione 
• 141693-80-3 3-phenyl-4-(p-tolyl)-1,2,4-thiadiazole-5(4H)-one 
• 63105-04-4 4-phenyl-3-p-tolyl-3H-[1,2,3,5]oxathiadiazole 2-oxide 
• 4300-33-8 N-(4-methylphenyl)-N'-phenylurea 

Relevant academic research and scientific papers

Synthesis and substituent effect study on 13C NMR chemical shifts of 4-(substitue-phenyl)-6-methyl-3-phenyl-4H-1,2,4-oxadiazin-5(6H)-one

The twelve novel 4-(substituted-phenyl)-6-methyl-3-phenyl-4H-1,2,4-oxadiazin-5(6H)-one derivatives were synthesized by the reactions of N-Substituted-phenyl-benzamide oximes with 2-bromopropionyl chloride. The synthesized 1,2,4-oxadiazin-5-one derivatives

Iodine Promoted One-Pot Synthesis of 2-Aryl Benzoxazoles from Amidoximes via Oxidative Cyclization and Ring Contraction

A molecular I2-promoted one-pot synthesis of 2-aryl benzoxazoles has been developed by using amidoximes rather than the limited 2-aminophenols or 2-haloamides as substrates. The amidoxime substrates provided unique and efficient strategies for converting readily available aniline and benzaldehyde precursors into valuable chemicals. This transformation proceeded smoothly under transition-metal-free conditions through a sequential oxidative cyclization and ring contraction, and provided a potential route for introducing certain groups at any site of the scaffold.

FeCl3·6H2O-mediated reaction of [60]fullerene with amidoximes

A FeCl3·6H2O-mediated reaction of [60]fullerene with amidoximes for the preparation of fulleroimidazolines has been presented. This reaction shows a wide substrate scope, and the products obtained from alkyl-substituted amidoximes ar

13C NMR substituent-induced chemical shifts in 4-(substituted phenyl)-3-phenyl-1,2,4-oxadiazol-5(4H)-ones (thiones)

In the present, study mostly novel ten 4-(substituted phenyl)-3-phenyl-1,2,4-oxadiazol-5(4H)-ones and ten 4-(substituted phenyl)-3-phenyl-1,2,4-oxadiazol-5(4H)-thiones were synthesized. These oxadiazole derivatives were characterized by IR, 1H

1,3-Dipolar Cycloaddition Reactions of 2,4,6-Cycloheptatrien-1-imines with Benzonitrile Oxides Leading to 1,2,4-Oxadiazaspiroundeca-2,6,8,10-tetraenes

1,3-Dipolar cycloaddition reactions of N-aryl-2,4,6-cycloheptatrien-1-imines with p-substituted benzonitrile oxides afforded -type cycloadducts in considerable yields.A study of the substituent effect on the reaction rate revealed that the reactions proceeded through nucleophilic reactions of imines to nitrile oxides.Thermal isomerizations and addition reactions of the adducts showed that the contribution of a valence isomerization between cycloheptatriene and norcaradiene lay to the side of the cycloheptatriene form.A comparison of the UV spectra between the adduct and its derivative, which was reduced by catalytic hydrogenation, implies that the spiroconjugation between cycloheptatriene and a five-membered heterocyclic moiety causes a shift of the equilibrium.