37024-73-0Relevant articles and documents
Titanium-Catalyzed Cyano-Borrowing Reaction for the Direct Amination of Cyanohydrins with Ammonia
Li, Qing-Hua,Li, Zhao-Feng,Tao, Jing,Li, Wan-Fang,Ren, Li-Qing,Li, Qian,Peng, Yun-Gui,Liu, Tang-Lin
supporting information, p. 8429 - 8433 (2019/10/14)
α-Aminonitrile was an important building block in natural products and key intermedia in organic chemistry. Herein, the direct amination of cyanohydrins with the partner of ammonia to synthesis N-unprotected α-aminonitriles is developed. The reaction proceeds via titanium-catalyzed cyano-borrowing reaction, which features high atom economy and simple operation. A broad range of ketone or aldehyde cyanohydrins was tolerated with ammonia, and the N-unprotected α-aminonitriles were synthesis with moderate to high yields under mild reaction conditions.
N-CYANOALKYLANTHRANILAMIDES AS INSECTICIDES
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Page/Page column 35, (2008/12/06)
Compounds of formula (I) wherein the substituents are as defined in claim 1, and the agrochemically acceptable salts and all stereoisomers and tautomeric forms of the compounds of formula (I) can be used as agrochemical active ingredients and can be prepa
N-Cyanoalkyl haloacetamides herbicidal antidotes
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, (2008/06/13)
Compounds having the formula STR1 in which R is 1-4 carbon haloalkyl; R1 is selected from the group consisting of hydrogen and 1-4 carbon alkyl; and R2 is selected from the group consisting of 2-8 carbon cyanoalkyl, 5-12 carbon cyano