370598-07-5Relevant academic research and scientific papers
Cascade synthesis of (E)-2-alkylidenecyclobutanols
Falck,Bandyopadhyay, Anish,Puli, Narender,Kundu, Abhijit,Reddy, L. Manmohan,Barma, Deb K.,He, Anyu,Zhang, Hongming,Kashinath, Dhurke,Baati, Rachid
supporting information; experimental part, p. 4764 - 4766 (2009/12/27)
A facile, one-pot reaction cascade condenses 1,1,1-trichloroalkanes with α,β-unsaturated ketones to unexpectedly furnish moderate to good yields of (E)-2-alkylidenecyclobutanols.
3,3,3-Trichloropropyl-1-triphenylphosphorane: A reagent for the synthesis of (Z)-1,3-enynes, (Z,Z)-1-chloro-1,3-dienes, and 1,3-diynes
Karatholuvhu, Maheswaran S.,Fuchs, Philip L.
, p. 14314 - 14315 (2007/10/03)
,3,3,3-Trichloropropyl-1-triphenylphosphonium chloride is conveniently prepared from 2-chloroethanol, triphenylphosphine, and trichloroacetic acid. Deprotonation of this reagent generates 3,3,3-trichloropropyl-1-triphenylphosphorane, which reacts with aldehydes to give trichloromethylated (Z)-olefins, which are useful for the synthesis of (Z)-1,3-enynes, (Z,Z)-1-chloro-1,3-dienes, and 1,3-diynes in high yields and stereospecificities. Copyright
A convenient synthesis of (Z)-1-chloro-1-alkenes and (Z)-1-chloro-2-alkoxy-1-alkenes
Baati, Rachid,Barma,Krishna, U.Murali,Mioskowski, Charles,Falck
, p. 959 - 961 (2007/10/03)
Mild, room temperature CrCl2 reduction of 1,1,1-trichloroalkanes stereoselectively generates (Z)-1-chloro-2-substituted-1-alkenes in excellent yields.
