3735-80-6Relevant academic research and scientific papers
Synthesis of Optically Active Cyclic Phosphorothionates and Phosphoramidothionates with Insecticidal Activity by Using a Chiral Phosphorylating Agent
Hirashima, Akinori,Eto, Morifusa
, p. 2831 - 2840 (2007/10/02)
Chiral methyl p-nitrophenyl phosphorochloridothionate (MNPC) was utilized as a phosphorylating agent in the synthesis of optically active cyclic phosphorus esters including the enantiomers of 2-methoxy-4H-1,3,2-benzodioxaphosphorin 2-sulfide (salithion) and four diastereomers of 4-isobutyl-2-methoxy-1,3,2-oxazaphospholidine 2-sulfide (BMOS).Their insecticidal activity decreased in the following order; (S) > (R) in salithion and (S)P(S)C > (S)P(R)C > (R)P(R)C > (R)P(S)C in BMOS.
Condensation products
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, (2008/06/13)
Formamidine compounds of the formula EQU1 or WHEREIN R1 represents a substituted or unsubstituted phenyl radical, R2 represents hydroogen, alkyl, alkenyl or alkinyl and R3 represents acyl their manufacture and their use in pest control.
