37418-36-3

Basic information

• Product Name: Benzene, [(1-methyl-1-propenyl)sulfonyl]-, (E)-
• CAS NO: 37418-36-3
• Molecular Formula: C10H12O2S
• Molecular Weight: 196.27
• Mol File: 37418-36-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzene, [(1-methyl-1-propenyl)sulfonyl]-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [(1-methyl-1-propenyl)sulfonyl]-, (E)-(37418-36-3)
• EPA Substance Registry System: Benzene, [(1-methyl-1-propenyl)sulfonyl]-, (E)-(37418-36-3)

Safety Data

• Hazardous Substances Data: 37418-36-3(Hazardous Substances Data)

Upstream product

• 37434-65-4 erythro-2-bromo-3-(phenylsulfonyl)butane 
• 16336-52-0 2-(phenylthio)-2-butene 
• 28074-23-9 phenylsulfenyl bromide 
• 98351-34-9 (1-Benzenesulfonyl-allyl)-trimethyl-silane 
• 873-55-2 sodium benzenesulfonate 
• 16212-05-8 (allylsulfonyl)benzene 
• 599-70-2 ethyl phenyl sulfone 
• 814-49-3 diethyl chlorophosphate 
• 75-07-0 acetaldehyde 
• 150583-30-5 (1-Benzenesulfonyl-1-methyl-allyl)-trimethyl-silane 

Downstream Products

• 590-18-1 (Z)-2-Butene 
• 107398-33-4 2-Methylsulfonyl-3-phenylsulfonyl butane 

Relevant articles and documents

One-pot synthesis of α-methyl vinyl sulfones from ethyl phenyl sulfones

Various α-methyl vinyl sulfones were synthesized by Horner-Emmons olefination of aldehydes and sulfonyl phosphonate generated from 1,1- dilithiosulfone.

Stereoselective preparation of vinyl sulfones by protodesilylation of allyl silanes

Allyl sulfones can be conjugated to furnish vinyl sulfones via allyl silane intermediates. The stereoselectivity observed in the protodesilylation step provides a new method for stereoselective preparation of (E)-di-and tri substituted vinyl sulfones.