98351-34-9Relevant academic research and scientific papers
Stereoselective preparation of vinyl sulfones by protodesilylation of allyl silanes
Funk, Raymond L.,Umstead-Daggett, Joy,Brummond, Kay M.
, p. 2867 - 2870 (2007/10/02)
Allyl sulfones can be conjugated to furnish vinyl sulfones via allyl silane intermediates. The stereoselectivity observed in the protodesilylation step provides a new method for stereoselective preparation of (E)-di-and tri substituted vinyl sulfones.
PALLADIUM CATALIZED OXIDATION OF ALLYLSILANES WITH U.V. LIGHT AND MOLECULAR OXIGEN
Riahi, A.,Cossy, J.,Muzart, J.,Pete, J. P.
, p. 839 - 842 (2007/10/02)
Photolysis of oxygenated acetone solutions of allylsilanes containing small amounts of palladium led to α,β-ethylenic alcohols, aldehydes or ketones.Efficient regiospecific oxidation can be observed when the allylsilane was substituted by an arylsulphonyl group.
