3744-07-8Relevant articles and documents
Simple N≡UF3 and P≡UF3 molecules with triple bonds to uranium
Andrews, Lester,Wang, Xuefeng,Lindh, Roland,Roos, Bjoern O.,Marsden, Colin J.
, p. 5366 - 5370 (2009/03/12)
UN-beatable? Laser-ablated uranium atoms activate NF3 and PF3 to form the N≡UF3 and P≡UF3 molecules containing novel terminal nitride and phosphide functional groups. These molecules are identified from matrix infrared spectra and theoretical methods. The N≡UF3 molecule contains the strongest triple bond to uranium in a ternary compound.
Electron affinities and gas-phase acidities of organogermanium and organotin compounds
Brinkman, Elizabeth A.,Salomon, Karen,Tumas, William,Brauman, John I.
, p. 4905 - 4910 (2007/10/02)
The electron affinities have been measured for trimethylgermanium and trimethyltin radicals as 31.9 ± 0.7 and 39.2 ± 1.5 kcal/mol, respectively, using electron photodetachment spectroscopy. The acidities (ΔH°acid) for the corresponding hydrides
