37457-03-7

Basic information

• Product Name: 2-p-Tolylsulfanyl-cyclohexanone
• CAS NO: 37457-03-7
• Molecular Weight: 220.335
• Mol File: 37457-03-7.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: 2-p-Tolylsulfanyl-cyclohexanone(CAS DataBase Reference)
• NIST Chemistry Reference: 2-p-Tolylsulfanyl-cyclohexanone(37457-03-7)
• EPA Substance Registry System: 2-p-Tolylsulfanyl-cyclohexanone(37457-03-7)

Safety Data

• Hazardous Substances Data: 37457-03-7(Hazardous Substances Data)

Upstream product

• 103-19-5 di(p-tolyl) disulfide 
• 108-94-1 cyclohexanone 
• 106-45-6 para-thiocresol 
• 822-87-7 2-Chlorocyclohexanone 
• 104871-67-2 (R)-2-(p-tolylsulfinyl)-1-cyclohexanone 
• 6873-93-4 1-[(4-methylphenyl)sulfinyl]piperidine 
• 6651-36-1 1-(Trimethylsilyloxy)cyclohexene 
• 10439-23-3 4-methylbenzenesulfinyl chloride 
• 536-57-2 p-toluene sulfinic acid 
• 56424-42-1 cyclohexylidene-(1-phenyl-ethyl)-amine 
• 110452-14-7 2-phenylthiocyclohexanone 
• 98-59-9 p-toluenesulfonyl chloride 
• 1056477-06-5 2-bromocyclohexanone 
• 2943-42-2 di(4-methyl)phenylthiosulfonate 

Downstream Products

• 260358-66-5 (+/-)-2-allyl-2-(p-toluenesulfenyl)cyclohexanone 
• 59010-83-2 1-methyl-4-(2-hydroxylphenyl)thiobenzene 
• 15922-43-7 1-benzyl-4,5,6,7-tetrahydro-1H-benzo[d][1,2,3]triazole 
• 771-98-2 1-Phenylcyclohexene 

Relevant articles and documents

Site-Selective Synthesis of Aryl Sulfides via Oxidative Aromatization of Cyclohexanones with Thiophenols

We have introduced a metal-free facile access for the thiolation/aromatization of cyclohexanones with thiophenols to the corresponding aryl sulfides. The dehydroaromatic reaction of non-aromatic cyclohexanones proceeded smoothly using oxygen as a green oxidant.

Synthesis of multisubstituted cycloalkenes through carbomagnesiation of strained cycloalkynes

An efficient synthetic method of seven- and six-membered cycloalkenes through the generation of strained cycloalkynes and following carbomagnesiation is described. Further bond formations of the resulting cycloalkenylmagnesium intermediates with a wide variety of electrophiles enabled us to prepare diverse cycloalkene derivatives including benzoxepine analogs having a fully substituted alkene structure.

Iodine-catalyzed efficient 2-arylsulfanylphenol formation from thiols and cyclohexanones

A novel method for the formation of 2-arylsulfanylphenols from thiols and cyclohexanones is described. Iodine was used as an effective catalyst for this kind of transformation. Cyclohexanones were used as a phenol source via a dehydrogenation and tautomerization reaction.