37526-86-6Relevant academic research and scientific papers
Direct carboxylation of allylic halides with carbon dioxide in the presence of indium
Miao, Bukeyan,Ma, Shengming
supporting information, p. 3285 - 3287 (2014/03/21)
A highly regioselective indium-mediated allylation of carbon dioxide starting from simple allylic halides (X = I, Br, Cl) has been developed. No transition metal catalyst is needed and an inert atmosphere is not necessary. The reaction tolerates a wide range of synthetically attractive functional groups with a very high branched regioselectivity. The Royal Society of Chemistry 2014.
Pd-catalyzed cross-coupling of potassium alkenyltrifluoroborates with 2-chloroacetates and 2-chloroacetamides
Molander, Gary A.,Barcellos, Thiago,Traister, Kaitlin M.
supporting information, p. 3342 - 3345 (2013/07/26)
A protocol for the stereocontrolled synthesis of (E)- and (Z)-β,γ-unsaturated esters and amides is reported. 2-Chloroacetates as well as secondary and tertiary 2-chloroacetamides were successfully employed as electrophiles in the Suzuki-Miyaura cross-coupling reaction with potassium (E)- and (Z)-alkenyltrifluoroborates, affording the corresponding products in high yield.
