37570-33-5Relevant academic research and scientific papers
Rationally Designed Fluorescence .OH Probe with High Sensitivity and Selectivity for Monitoring the Generation of .OH in Iron Autoxidation without Addition of H2O2
Li, Hongyu,Li, Xiaohua,Shi, Wen,Xu, Yanhui,Ma, Huimin
supporting information, p. 12830 - 12834 (2018/09/12)
The first sensitive fluorescence .OH probe (1) that is capable of monitoring the generation of trace .OH in iron autoxidation is presented. The probe 1 was designed by utilizing both the unique aromatic hydroxylation and the electrop
Steric control of site selectivity in the Pd-catalyzed C-H acetoxylation of simple arenes
Cook, Amanda K.,Emmert, Marion H.,Sanford, Melanie S.
supporting information, p. 5428 - 5431 (2013/11/19)
This report describes the use of an oxidant and a ligand to control site selectivity in the Pd(OAc)2-catalyzed C-H acetoxylation of simple arenes. The use of MesI(OAc)2 as the terminal oxidant in combination with acridine as the ligand results in primarily sterically controlled selectivity. In contrast, with Pd(OAc)2 as the catalyst and PhI(OAc)2 as the oxidant, electronic effects dominate the selectivity of arene C-H acetoxylation.
