37580-41-9

Basic information

• Product Name: Benzene, (1-ethenyl-1-propenyl)-
• CAS NO: 37580-41-9
• Molecular Formula: C11H12
• Molecular Weight: 144.216
• Mol File: 37580-41-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzene, (1-ethenyl-1-propenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, (1-ethenyl-1-propenyl)-(37580-41-9)
• EPA Substance Registry System: Benzene, (1-ethenyl-1-propenyl)-(37580-41-9)

Safety Data

• Hazardous Substances Data: 37580-41-9(Hazardous Substances Data)

Upstream product

• 4743-68-4 3-phenyl-4-methyl-3-buten-2-ol 
• 859487-58-4 2-methyl-3-phenyl-2,5-dihydro-thiophene-1,1-dioxide 
• 4411-89-6 (E/Z)-2-phenylcrotonaldehyde 
• 93-55-0 1-phenyl-propan-1-one 
• 31254-19-0 1-Ethyl-1-phenylallyl alcohol 
• 1311260-13-5 tert-butyl (3-phenylpent-1-en-3-yl) carbonate 
• 72824-04-5 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 122-78-1 phenylacetaldehyde 
• 4411-89-6 2-phenyl-2-butenal 
• 19493-09-5 Methylenetriphenylphosphorane 

Downstream Products

• 859487-58-4 2-methyl-3-phenyl-2,5-dihydro-thiophene-1,1-dioxide 
• 115363-11-6 2-methyl-[1,1’-biphenyl]-3-carboxylic acid 
• 178313-67-2 2-methyl[1,1'-biphenyl]-4-carboxylic acid 
• 87567-37-1 C₂₁H₂₆O₂S 
• 87567-35-9 1-(Neophylsulfonyl)-3-phenyl-(E)-pent-3-ene 
• 954-06-3 biphenyl-2,3-dicarboxylic acid anhydride 
• 92686-59-4 C₂₀H₁₉NS₂ 
• 92686-59-4 C₂₀H₁₉NS₂ 

Relevant articles and documents

Enantioselective construction of all-carbon quaternary centers by branch-selective Pd-catalyzed allyl-allyl cross-coupling

The Pd-catalyzed cross-coupling of racemic tertiary allylic carbonates and allylboronates is described. This reaction generates all-carbon quaternary centers in a highly regioselective and enantioselective fashion. The outcome of these reactions is consistent with a process that proceeds by way of 3,3′-reductive elimination of bis(η1-allyl)palladium intermediates. Strategies for distinguishing the product alkenes and application to the synthesis of (+)-α-cuparenone are also described.

Regio- and Stereoselective Hydrosulfonylation of Conjugated Dienes via a (?-Allyl)palladium Complex

The combination of a sulfonylpalladation of acyclic dienes 1 (with 2 equiv of NaSO2R and 1 equiv of PdCl2 in acetic acid or acetic acid-H2O at 50-80 deg C under air) and a protiodepalladation of the thus obtained palladium complexes 3 with dimethylglyoxime (in a protic solvent at room temperature) provides di- and trisubstituted (Z)-Δ3-sulfones 12 selectively, irrespective of the stereochemistry of the starting dienes.Similar treatment of 1-vinylcycloalkenes 5 (n (1,3) strain between Pd and the substituent on the allylic position.