37591-83-6Relevant academic research and scientific papers
PhICl2 and wet DMF: An efficient system for regioselective chloroformyloxylation/a-chlorination of alkenes/a,β-unsaturated compounds
Liu, Le,Zhang-Negrerie, Daisy,Du, Yunfei,Zhao, Kang
supporting information, p. 436 - 439 (2014/04/03)
PhICl2 in wet DMF was found to form an efficient system for realizing difunctionalization of various alkenes and olefinic derivatives possessing a wide range of functional groups. This novel methodology provides convenient access to either regioselective chloroformyloxylated products or a-chlorinated olefinic products, depending on the type of structure of the original unsaturated starting material. The mechanism of the reaction is proposed and discussed.
SOLVENT SHIFTS INDUCED BY DIMETHYLSULPHOXIDE IN α-PROTON MAGNETIC RESONANCES OF CARBONYL COMPOUNDS
Cabaliero, M. C.,Giagante, N. N.
, p. 1829 - 1832 (2007/10/02)
The chemical shifts of α- and β-proton resonances of a number of carbonyl compounds in carbon tetrachloride and dimethylsulphoxide have been determined.The magnitude of the effect of the solvent change on the α-proton resonances seems to vary directly wit
