37605-80-4

Upstream product

• 37605-53-1 1-((E)-2-Benzenesulfinyl-1-phenylsulfanyl-vinyl)-cyclohexanol 
• 69190-57-4 <1,1-bis(phenylthio)methylene>cyclohexane 
• 68-12-2 N,N-dimethyl-formamide 
• 931-59-9 benzenesulfenyl chloride 
• 37605-51-9 2-Phenyl-4-phenylsulfanyl-1-oxa-2-thionia-spiro[4.5]dec-3-ene; chloride 
• 89005-21-0 C₂₀H₂₀OS₂ 
• 78-27-3 1-Ethynylcyclohexan-1-ol 
• 930-69-8 sodium thiophenolate 
• 108-94-1 cyclohexanone 
• 59377-31-0 ((E)-2-Ethoxy-vinylsulfanyl)-benzene 
• 89005-27-6 1-((Z)-1,2-Bis-phenylsulfanyl-vinyl)-cyclohexanol 
• 77003-98-6 ((Z)-1-Cyclohex-1-enyl-2-methoxy-vinylsulfanyl)-benzene 

Relevant academic research and scientific papers

The First Example of the 1-Chalcogene-Substituted Formylolefination of the Ketones and Aldehydes Using 1-Lithio-2-ethoxyvinyl Chalcogenides

The α-chalcogene-substituted formylolefinations of ketones and aldehydes proceeded using 1-lithio-2-ethoxyvinyl chalcogenides/PPSE or TMSOTf to produce the α-chalcogenoformylolefinated products 4a-l in high yields. Tandem-formylolefmation provided the (2Z,4Z)-2,4-bis(chalcogeno)pent-2,4-dienals 5d,h,i and (2Z,4Z,6Z)-2,4,6-tris(phenylthio)hept-2,4,6-trienal derivatives 7d and 8d, respectively.

Chemistry of Allene Sulphoxides: Novel Transformations of Acetylenic Alcohols

The preparation and reactions of allenes derived from 1-phenylthio substituted acetylenic alcohols are described; this chemistry offers new routes to allenyl sulphides, acyl anion equivalents, and substituted unsaturated aldehydes.

RAPID, HIGH YIELD CLEAVAGE OF ENOL AND DIENOL METHYL ETHERS UNDER MILD CONDITIONS USING CHLOROTRIMETHYLSILANE/SODIUM IODIDE

A number of enol and dienol methyl ethers are rapidly cleaved to aldehydes and ketones in quantitative yields by the use of chlorotrimethylsilane/sodium iodide.