37822-98-3

Basic information

• Product Name: AuCl₂(P(C₆H₅)3)(C₆F₅)
• CAS NO: 37822-98-3
• Molecular Weight: 697.221
• Mol File: 37822-98-3.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: AuCl₂(P(C₆H₅)3)(C₆F₅)(CAS DataBase Reference)
• NIST Chemistry Reference: AuCl₂(P(C₆H₅)3)(C₆F₅)(37822-98-3)
• EPA Substance Registry System: AuCl₂(P(C₆H₅)3)(C₆F₅)(37822-98-3)

Safety Data

• Hazardous Substances Data: 37822-98-3(Hazardous Substances Data)

Upstream product

• 932-72-9 (Dichloroiodo)benzene 
• 616-47-7 1-methyl-1H-imidazole 

Downstream Products

• 165268-46-2 [Au(C₆F₅)(1,3-dithiol-2-thione-4,5-dithiolate)(PPh₃)] 
• 165268-44-0 [Au(C₆F₅)(1,2-benzenedithiolate)(PPh₃)] 
• 165268-45-1 [Au(C₆F₅)(3,4-toluenedithiolate)(PPh₃)] 
• 201849-90-3 Au(S₂C₂B₁₀H₁₀)(C₆F₅)(P(C₆H₅)3) 
• 14243-64-2 (triphenylphosphine)gold(I) chloride 
• 434-90-2 decafluorobiphenyl 
• 1244039-16-4 1-methyl-3-(perfluorophenyl)-1H-indole 
• 1261568-74-4 2,2’,3,4,4’,5,6,6’-octafluorobiphenyl 
• 372-38-3 1,3,5-trifluorobenzene 
• 363-72-4 Pentafluorobenzene 

Relevant articles and documents

A neutral Gold(III)-Boron transmetalation

The occurrence of direct transmetalation between gold(III) and boron species during gold-catalyzed cross-coupling reactions has recently become the subject of intense discussion. In this work, we investigate the transmetalation reaction between discrete, stable gold(III) complexes and boron reagents. Interestingly, electron-rich arylboronic acids remain unreactive under neutral conditions, whereas electron-deficient species undergo transmetalation in a highly efficient manner.

Unexpected outcomes of the oxidation of (pentafluorophenyl) triphenylphosphanegold(I)

Redox gold(I)/gold(III) catalytic cycles have been proposed as the productive mechanistic manifold in a number of gold mediated C-C and C-X bond forming reactions. These transformations rely on the use of stoichiometric oxidants such as iodonium salts and