37822-98-3

Upstream product

• 932-72-9 (Dichloroiodo)benzene 
• 616-47-7 1-methyl-1H-imidazole 

Downstream Products

• 165268-44-0 [Au(C₆F₅)(1,2-benzenedithiolate)(PPh₃)] 
• 165268-46-2 [Au(C₆F₅)(1,3-dithiol-2-thione-4,5-dithiolate)(PPh₃)] 
• 165268-45-1 [Au(C₆F₅)(3,4-toluenedithiolate)(PPh₃)] 
• 14243-64-2 (triphenylphosphine)gold(I) chloride 
• 434-90-2 decafluorobiphenyl 
• 1244039-16-4 1-methyl-3-(perfluorophenyl)-1H-indole 
• 1261568-74-4 2,2’,3,4,4’,5,6,6’-octafluorobiphenyl 
• 372-38-3 1,3,5-trifluorobenzene 
• 363-72-4 Pentafluorobenzene 
• 201849-90-3 Au(S₂C₂B₁₀H₁₀)(C₆F₅)(P(C₆H₅)3) 

Relevant academic research and scientific papers

A neutral Gold(III)-Boron transmetalation

The occurrence of direct transmetalation between gold(III) and boron species during gold-catalyzed cross-coupling reactions has recently become the subject of intense discussion. In this work, we investigate the transmetalation reaction between discrete, stable gold(III) complexes and boron reagents. Interestingly, electron-rich arylboronic acids remain unreactive under neutral conditions, whereas electron-deficient species undergo transmetalation in a highly efficient manner.

Cross-coupling of arene-gold(III) complexes

The reactivity of electron-deficient arene-gold(III) complexes toward nucleophilic aromatic and heteroaromatic counterparts has been studied. 1-Methylindole proved to be the best reaction partner while trimethoxybenzenes did not react. The ancillary ligand on gold also influenced the reactivity in the order PPh3>PtBu3>IPr. An oxidative cross-coupling starting from the corresponding gold(I) complexes in presence of hypervalent iodide oxidants was also studied.

Unexpected outcomes of the oxidation of (pentafluorophenyl) triphenylphosphanegold(I)

Redox gold(I)/gold(III) catalytic cycles have been proposed as the productive mechanistic manifold in a number of gold mediated C-C and C-X bond forming reactions. These transformations rely on the use of stoichiometric oxidants such as iodonium salts and

DIHALO PENTAFLUOROPHENYL TETRAHYDROTHIOPHEN GOLD(III) COMPLEXES, THEIR PREPARATION AND REACTIONS

The complex Au(C6F5)(tht) undergoes oxidative addition when treated in solution with halogens, to give Au(C6F5)X(tht) (X=Cl, Br or I).The tetrahydrothiophen ligand of the latter can be displaced by neutral or anionic ligands to give, respectively, the neu