37834-22-3Relevant academic research and scientific papers
METALLKOMPLEXIERTE SULFINYLPHOSPHINITE ALS INTERMEDIATE BEI DER BILDUNG VON DIPHOSPHOXAN-KOMPLEXEN. SYNTHESE, EIGENSCHAFTEN UND STRUKTUR VON μ-(TETRAPHENYLDIPHOSPHOXAN)BIS-KOMPLEXEN, O (M=Cr, Mo, W)
Zeiher, C.,Mohyla, J.,Lorenz, I. P.,Hiller, W.
, p. 159 - 170 (2007/10/02)
The diphenylphosphane complexes (CO)5MP(C6H5)2H (M=Cr,Mo,W) (Ia-Ic) react with sulfonyl chlorides, RSO2Cl, (R=CH3, p-CH3C6H4) in diethyl ether via the non-isolable sulfinylphosphinito-P complexes (CO)5M (IIa-IIc) to give the homogeneous anhydrides, the diphodoxane complexes 2O (IIIa-IIIc) and the sulfinylsulfolanes R(O)SS(O)2R.The composition and structures of complexes III result from the IR, 31P NMR and mass spectra.The crystal structure of IIIa has been determined IIIa crystalliyes in the space group Cc.Two nearly octahedrally arranged (CO)5CrP(C6H5)2 moieties are joined by an unsymmetrical oxygen-bridge in the all-trans position, the bond angle P(1)-OP(2) being 145 deg.
Synthesis and a multinuclear NMR spectroscopic study of some Mo(CO)5(PPh2XR) (X = O, NH; R = 1-4 carbon alkyls) complexes. Steric effects on 31P and 95Mo chemical shifts
Gray, Gary M.,Gray, Rita June
, p. 1026 - 1031 (2008/10/08)
The syntheses and multinuclear NMR spectroscopic data for a series of Mo(CO)5(PPh2XR) (X = O, NH; R = 1-4 carbon alkyls) complexes is presented. The steric effect of substitution at the α carbon of the R groups is shown to have an effect on the chemical shifts of the aromatic C(1) 13C 31P, and 95Mo resonances but not upon the chemical shifts of the carbonyl 13C and 17O resonances. In addition, the good correlation observed between the chemical shifts of the 95Mo and aromatic C(1) 13C resonances indicates that in the Mo(CO)5(PPh2XR) complexes, the 95Mo and aromatic C(1) 13C resonances are similarly affected by changes in the R group.
