37868-74-9

Basic information

• Product Name: 2-Propenal, 3-cyclohexyl-, (E)-
• Synonyms: (E)-3-cyclohexyl-2-propen-1-al;2-(E)-3-cyclohexyl-2-propenal;(E)-3-cyclohexylacrylacrolein;2-Propenal,3-cyclohexyl-,(E);(E)-3-cyclohexylpropenal;3-cyclohexylacrylaldehyde;(E)-3-cyclohexylacrylaldehyde;2-Propenal,3-cyclohexyl;(E)-3-cyclohexyl-2-propenal
• CAS NO: 37868-74-9
• Molecular Formula: C9H14O
• Molecular Weight: 138.21
• Mol File: 37868-74-9.mol
• Article Data: 40

Chemical Properties

• CAS DataBase Reference: 2-Propenal, 3-cyclohexyl-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propenal, 3-cyclohexyl-, (E)-(37868-74-9)
• EPA Substance Registry System: 2-Propenal, 3-cyclohexyl-, (E)-(37868-74-9)

Safety Data

• Hazardous Substances Data: 37868-74-9(Hazardous Substances Data)

Usage

Synthesis Reference(s)

Journal of the American Chemical Society, 99, p. 7365, 1977 DOI: 10.1021/ja00464a051Tetrahedron Letters, 34, p. 341, 1993 DOI: 10.1016/S0040-4039(00)60583-X

Upstream product

• 56453-86-2 (E)-3-cyclohexylprop-2-enoic acid 
• 75-07-0 acetaldehyde 
• 2043-61-0 cyclohexanecarbaldehyde 
• 137345-53-0 (E)-1-Cyclohexyl-3-phenylselanyl-prop-2-en-1-ol 
• 108-94-1 cyclohexanone 
• 114273-73-3 (3-methoxy-2E-propylidene)triphenylphosphorane 
• 2114-42-3 allylcyclohexane 
• 6048-09-5 3-cyclohexylacrylic acid ethyl ester 
• 1611-78-5 1,3-bis-dimethylaminotrimethinium perchlorate 
• 931-50-0 cyclohexylmagnesium bromide 
• 3054-95-3 acrylaldehyde diethyl acetal 
• 626-62-0 Cyclohexyl iodide 
• 4352-44-7 1-cyclohexylprop-2-en-1-ol 
• 2136-75-6 (triphenylphosphoranylidene)acetaldehyde 

Downstream Products

• 194807-81-3 triisopropyl 7-cyclohexylhepta-3E,6E-dienoate 
• 114180-63-1 (E)-2-(4-cyclohexylbut-3-en-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 66938-07-6 (3R)-3-cyclohexylbutanal 
• 110065-44-6 (3S)-3-cyclohexylbutanal 
• 137151-90-7 (R)-3-cyclohexylpentanal 
• 1033750-81-0 C₉H₁₅NO 
• 1161512-46-4 5-cyclohexyl-2-isoxazoline 
• 1252007-00-3 C₂₁H₂₈N₂O₄ 
• 1259027-62-7 (R)-2-(cyclohexylidenemethyl)-3,3-bis(4-(dimethylamino)phenyl)propanal 
• 1259027-69-4 (E)-3-(1-(bis(4-(dimethylamino)phenyl)methyl)cyclohexyl)acrylaldehyde 

Relevant articles and documents

X-RAY STRUCTURE OF A CHIRAL ALKENE: DIRECT EVIDENCE FOR C-H BOND ECLIPSING C=C BOND

A single crystal X-ray structure determination of the chiral alkene, (1Z)-1-(benzyloxymethyloxy)-3-cyclohexyl-4-phenyl-1-buten-4-ol, (1), is described.The observed conformation about the Csp2-Csp3 bond of 1 is the C-H eclipsed form in the crystal and in solution.The observed torsional angles in the acetal portion of the structure are -65 deg for R'-O-C-O and -59 deg for O-C-O-R''.

Sulfur-controlled and rhodium-catalyzed formal (3 + 3) transannulation of thioacyl carbenes with alk-2-enals and mechanistic insights

A rhodium-catalyzed denitrogenative formal (3 + 3) transannulation of 1,2,3-thiadiazoles with alk-2-enals is achieved, producing 2,3-dihydrothiopyran-4-ones in moderate to excellent yields. An inverse KIE of 0.49 is obtained, suggesting the reversibility of the oxidative addition of thioacyl Rh(i) carbenes to alk-2-enals. The late-stage structural modifications of steroid compounds are realized. Moreover, our studies show that thioacyl carbenes have different reactivities to those of α-oxo and α-imino carbenes, and highlight the importance of heteroatoms in deciding the reactivities of heterovinyl carbenes.

Palladium-catalysed regio- And stereoselective arylative substitution of γ,δ-epoxy-α,β-unsaturated esters and amides by sodium tetraaryl borates

Palladium-catalysed reactions of γ,δ-epoxy-α,β-unsaturated esters and amides with NaBAr4 reagents proceeded regio- and stereoselectively, producing allylic homoallyl alcohols with aryl-substituents in the allylic position for a wide range of substrates. A