
Tetrahedron Letters p. 713 - 716 (1992)
Update date:2022-08-16
Topics:
Gung, Benjamin W.
Karipides, Anastas
Wolf, Mark A.
A single crystal X-ray structure determination of the chiral alkene, (1Z)-1-(benzyloxymethyloxy)-3-cyclohexyl-4-phenyl-1-buten-4-ol, (1), is described.The observed conformation about the Csp2-Csp3 bond of 1 is the C-H eclipsed form in the crystal and in solution.The observed torsional angles in the acetal portion of the structure are -65 deg for R'-O-C-O and -59 deg for O-C-O-R''.
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