37935-79-8Relevant academic research and scientific papers
Chromium(II)-mediated synthesis of vinylbis(silanes) from aldehydes and a study of acid- and base-induced reactions of the derived epoxybis(silanes): A synthesis of acylsilanes
Hodgson, David M.,Comina, Paul J.,Drew, Michael G. B.
, p. 2279 - 2289 (2007/10/03)
The synthesis of vinylbis(silanes) 1 from aldehydes and dibromomethylenebis(trimethylsilane) using chromium(II) chloride in DMF is described. Epoxidation of vinylbis(silanes) 1 and treatment of the resulting epoxybis(silanes) 2 with sulfuric acid in metha
A remarkable base-induced rearrangement of epoxydisilanes
Hodgson, David M.,Comina, Paul J.
, p. 5613 - 5614 (2007/10/03)
The LDA-induced rearrangements of epoxydisilane 1 (R = Ph), to give predominantly β-trimethylsilyl acylsilane 6 (R = Ph), and of epoxydisilanes 1 (R = alkyl) remarkably to give silanols 7, are described.
A novel synthesis of acylsilanes
Nakada, Masahisa,Nakamura, Sei-Ichi,Kobayashi, Susumu,Ohno, Masaji
, p. 4929 - 4932 (2007/10/02)
A mild and general preparative method for acylsilane is presented. This novel method can be applied without any difficulty to α-chiral, α-alkoxy and multifunctionalized compounds.
