37985-08-3Relevant academic research and scientific papers
Design, Synthesis, and Application of Polymer-Supported Silicon-Transfer Agents for Cross-Coupling Reactions with Organolithium Reagents
Nguyen, Minh H.,O'Brien, Kevin T.,Smith, Amos B.
, p. 11056 - 11071 (2017)
The initial design, synthesis, and validation of polymer-supported siloxane transfer agents have been achieved that permit the direct use of organolithium reagents in the palladium-catalyzed cross-coupling reactions. Through rational design, two generations of polymer support were developed that significantly simplify product purification and the transfer agent recycling.
Polymer-supported siloxane transfer agents for Pd-catalyzed cross-coupling reactions
Nguyen, Minh H.,Smith, Amos B.
supporting information, p. 4258 - 4261 (2013/09/12)
The design, synthesis, and validation of a ring-opening metathesis polymerization (ROMP) polymer supporting siloxane transfer agents have been achieved that permit efficient palladium-catalyzed cross-coupling reactions. The solubility properties of the polymer facilitate not only product purification but also polymer recycling without significant loss of cross-coupling activity.
Stereocontrolled formation of styrenes by Pd(0)-catalyzed cross-coupling of photoactivated (E)-Alkenylgermanes with aryl bromides
Tseng, Chih-Chung,Li, Mungyuen,Mo, Bingli,Warren, Sarah A.,Spivey, Alan C.
supporting information; experimental part, p. 995 - 997 (2011/12/05)
The stereocontrolled synthesis of (E)-configured styrenes via Pd(0)-catalyzed cross-couping of (E)-alkenylgermanes with aryl bromides is described. The germanes employed have bis(naphthalen- 2-ylmethyl) substitution to allow photooxidative activation towa
