38209-58-4Relevant articles and documents
Catalytic Activation of Carbon-Hydrogen Bonds in Lignin Linkages over Strong-Base-Modified Covalent Triazine Frameworks for Lignin Oxidative Cleavage
Gao, Jin,Liu, Meng,Shi, Song,Xu, Jie,Zhao, Li,Zhu, Guozhi
, p. 7526 - 7534 (2020/08/21)
The design of highly efficient catalysts for the cleavage of various lignin linkages is the key step in the depolymerization of lignin. In this paper, strong-base-modified covalent triazine frameworks (CTFs) were reported to be effective in the cleavage o
New method for preparing alpha-bromo-3,4-dimethoxyphenylacetic trichloroethanol ester
-
Paragraph 0011; 0012, (2019/01/08)
The invention discloses a method for preparing a key intermediate alpha-bromo-3,4-dimethoxyphenylacetic trichloroethanol ester for synthesis of Baculiferin L. the method comprises the following steps:1) using 1,2-dimethoxylphenyl (CAS: 91-16-7) and methyl
Development of a simple system for the oxidation of electron-rich diazo compounds to ketones
O'Connor, Nicholas R.,Bolgar, Peter,Stoltz, Brian M.
, p. 849 - 851 (2016/02/05)
Mild heating of diazo compounds in DMSO furnishes ketone products in moderate to excellent yields. The reaction is particularly effective on electron-rich substrates and exhibits high chemoselectivity, allowing for the use of diazo compounds containing additional oxidation-prone functional groups. This straightforward protocol offers an alternate route to synthetically useful α-ketoesters from readily available aryl diazoacetates.