38306-41-1Relevant academic research and scientific papers
Microwave-assisted domino hydroformylation/cyclization reactions: Scope and limitations
Airiau, Etienne,Chemin, Claire,Girard, Nicolas,Lonzi, Giacomo,Mann, Andre,Petricci, Elena,Salvadori, Jessica,Taddei, Maurizio
experimental part, p. 2901 - 2914 (2010/10/21)
Hydroformylation of alkenes can be carried out in short time and with low syngas pressure under microwave (MW) dielectric heating. Alkenes, carrying O-, N-, or C-nucleophilic fragments, can be designed for domino reactions, mainly cyclocondensations. Ally
NMR Studies of Bond Orders in Heteroaromatic Systems
Hatton, Paul M.,Sternhell, Sever
, p. 935 - 946 (2007/10/02)
Fifty-seven for the ortho-benzylic coupling constant 4JMe-C=C-H (henceforth denoted as 4JOB) were obtained for a variety of heteroaromatic systems.It was shown that a good correlation exists between 4JOB when the methyl group is not α to the heteroatom and the SCF-MO bond order.This method can therefore be used as experimental means of determining bond orders in heteroaromatic systems.An examination of bond alternation in thirteen heteroaromatic systems has given a measure of relative "degree of aromaticity" for a larger number of systems than previously r eported by any single method.
