383187-80-2

Upstream product

• 5673-07-4 2,6-dimethoxytoluene 
• 383187-30-2 propionic acid 2,4-dimethoxy-3-methylphenyl ester 
• 383187-65-3 (4S,5R,6R)-4-[(S)-2-(4-Methoxy-benzyloxy)-1-methyl-ethyl]-2,2,5-trimethyl-6-(2,3,5-trimethoxy-4-methyl-phenyl)-[1,3]dioxane 
• 383187-60-8 (1R,2S,4S)-1-Hydroxy-5-(4-methoxy-benzyloxy)-2,4-dimethyl-1-(2,3,5-trimethoxy-4-methyl-phenyl)-pentan-3-one 
• 383187-47-1 (2R,3S,4S)-3-Hydroxy-5-(4-methoxy-benzyloxy)-2,4-dimethyl-1-(2,3,5-trimethoxy-4-methyl-phenyl)-pentan-1-one 
• 383187-63-1 (1R,2R,3S,4S)-5-(4-Methoxy-benzyloxy)-2,4-dimethyl-1-(2,3,5-trimethoxy-4-methyl-phenyl)-pentane-1,3-diol 
• 383187-35-7 1-(2-hydroxy-3,5-dimethoxy-4-methyl-phenyl)-propan-1-one 
• 383187-40-4 1-(2,3,5-trimethoxy-4-methyl-phenyl)-propan-1-one 
• 182193-69-7 (S)-1-(p-methoxybenzyloxy)-2-methylpentan-3-one 
• 85071-59-6 1-bromo-2,3,5-trimethoxy-4-methylbenzaldehyde 
• 77942-13-3 2',4'-dimethoxy-3'-methylpropiophenone 
• 383187-73-3 (S)-2-[(4S,5R,6R)-2,2,5-Trimethyl-6-(2,3,5-trimethoxy-4-methyl-phenyl)-[1,3]dioxan-4-yl]-propan-1-ol 

Downstream Products

• 383187-77-7 (E)-(2R,6S)-1-(tert-Butyl-diphenyl-silanyloxy)-2-methyl-6-[(4S,5R,6R)-2,2,5-trimethyl-6-(2,3,5-trimethoxy-4-methyl-phenyl)-[1,3]dioxan-4-yl]-hept-4-en-3-one 
• 383187-79-9 (2R,3R,4S,5R,6R)-2-[(S)-4-(tert-Butyl-diphenyl-silanyloxy)-3-methyl-butyl]-3,5-dimethyl-6-(2,3,5-trimethoxy-4-methyl-phenyl)-tetrahydro-pyran-4-ol 
• 383187-78-8 (R)-4-(tert-Butyl-diphenyl-silanyloxy)-1-[(2R,3R,4S,5R,6R)-4-hydroxy-3,5-dimethyl-6-(2,3,5-trimethoxy-4-methyl-phenyl)-tetrahydro-pyran-2-yl]-3-methyl-butan-2-one 

Relevant academic research and scientific papers

Synthesis of the C1-C13 fragment of kendomycin: Atropisomerism around a C-aryl glycosidic bond

The left-hand fragment 2 of the novel antibiotic kendomycin (1) has been synthesized by an aldol addition of a C5 alcohol with a C9-C11 enone. Compound 2 shows an interesting atropisomerism around the C4a-C5-sp2-sp3 bond. The atropis