77942-13-3 Usage
Preparation
Preparation by methylation of 2,4-dihydroxy- 3-methyl-propiophenone with dimethyl sulfate in the presence of potassium carbonate in refluxing acetone for 48 h (86%).
Check Digit Verification of cas no
The CAS Registry Mumber 77942-13-3 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 7,7,9,4 and 2 respectively; the second part has 2 digits, 1 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 77942-13:
(7*7)+(6*7)+(5*9)+(4*4)+(3*2)+(2*1)+(1*3)=163
163 % 10 = 3
So 77942-13-3 is a valid CAS Registry Number.
InChI:InChI=1/C12H16O3/c1-5-10(13)9-6-7-11(14-3)8(2)12(9)15-4/h6-7H,5H2,1-4H3
77942-13-3Relevant articles and documents
Synthesis of the C1-C13 fragment of kendomycin: Atropisomerism around a C-aryl glycosidic bond
Martin, Harry J.,Drescher, Martina,Khlig, Hanspeter,Schneider, Sabine,Mulzer, Johann
, p. 3186 - 3188 (2007/10/03)
The left-hand fragment 2 of the novel antibiotic kendomycin (1) has been synthesized by an aldol addition of a C5 alcohol with a C9-C11 enone. Compound 2 shows an interesting atropisomerism around the C4a-C5-sp2-sp3 bond. The atropis