90525-97-6

Upstream product

• 1308658-42-5 C₁₄H₂₀BNO₃ 
• 3839-35-8 4-methylbenzenesulfonic acid n-hexylester 
• 111-27-3 hexan-1-ol 
• 405520-68-5 4-(N,N-dimethylaminocarbonyl)phenylboronic acid 
• 14062-80-7 N,N-dimethyl-4-chlorobenzamide 
• 44767-62-6 n-hexylmagnesium chloride 
• 3761-92-0 n-hexylmagnesium bromide 

Relevant academic research and scientific papers

Iron-Catalyzed C(sp2)?C(sp3) Cross-Coupling of Chlorobenzamides with Alkyl Grignard Reagents: Development of Catalyst System, Synthetic Scope, and Application

Direct preparation of alkylated amide-derivatives by cross-coupling chemistry using sustainable protocols is challenging due to sensitivity of the amide functional group to reaction conditions. Herein, we report the synthesis of alkyl-substituted amides b

Copper-catalyzed cross-coupling reaction of organoboron compounds with primary alkyl halides and pseudohalides

Non-activated alkyl electrophiles, including alkyl iodides, bromides, tosylates, mesylates, and even chlorides, underwent copper-catalyzed cross-coupling with aryl boron compounds and alkyl 9-BBN reagents (see scheme; 9-BBN=9-borabicyclo[3.3.1]nonane). The reactions proceed with practically useful reactivities and thus complement palladium- and nickel-catalyzed Suzuki-Miyaura coupling reactions of alkyl halides.