383908-65-4Relevant academic research and scientific papers
Cleavage of Calkyl-Caryl bond of [Pd-CH2CMe2Ph] complexes
Campora, Juan,Gutierrez-Puebla, Enrique,Lopez, Jorge A.,Monge, Angeles,Palma, Pilar,Rio, Diego Del,Carmona, Ernesto
, p. 3641 - 3644 (2001)
The extrusion of isobutene from the neophyl derivative 1 is catalyzed by the cationic palladium π-arene complex 2 in a process that involves the cleavage of the β C-C bond of the latter (see scheme). The inverse reactivity, that is olefin insertion, is observed when the reaction proceeds in the presence of ethylene.
