38445-61-3Relevant articles and documents
New oxidative transformations of alkenes and alkynes under the action of diacetoxyiodobenzene
Yusubov,Zholobova,Filimonova,Chi, Ki-Whan
, p. 1735 - 1742 (2007/10/03)
Treatment of alkenes and alkynes with diacetoxyiodobenzene activated by mineral and organic acids predominantly results in oxidative rearrangement. 1,4-Diphenylbutadiene in MeOH gives 3,4-dimethoxy-1,4-diphenylbut-1-ene.
The reaction of cyclic allylic alcohols with aliphatic alcohols in the presence of cerium(III) chloride
Uzarewicz,Dresler
, p. 181 - 195 (2007/10/03)
Cyclic secondary and tertiary allylic alcohols react with primary aliphatic alcohols in the presence of cerium(III) chloride heptahydrate to give alkyl allylic ethers. When secondary or tertiary aliphatic alcohols are used 1,3-dienes are obtained from allylic alcohols heaving the 3-methyl-2-en-1-ol moiety (3-8, 13-15).
Anti-Markovnikov Addition of Nucleophiles to a Non-conjugated Olefin via Single Electron Transfer Photochemistry
Gassman, Paul G.,Bottorff, Kyle J.
, p. 5449 - 5452 (2007/10/02)
Nucleophilic solvent has been added regiospecifically in an anti-Markovnikov manner to a simple non-conjugated olefin, 1-methylcyclohexene, through single electron transfer induced photochemistry using the 1-cyanonaphthalene - biphenyl pair for achieving photooxidation.