38445-61-3Relevant academic research and scientific papers
New oxidative transformations of alkenes and alkynes under the action of diacetoxyiodobenzene
Yusubov,Zholobova,Filimonova,Chi, Ki-Whan
, p. 1735 - 1742 (2007/10/03)
Treatment of alkenes and alkynes with diacetoxyiodobenzene activated by mineral and organic acids predominantly results in oxidative rearrangement. 1,4-Diphenylbutadiene in MeOH gives 3,4-dimethoxy-1,4-diphenylbut-1-ene.
Reaction of cyclic allylic acetates with aliphatic alcohols in the presence of cerium(III) chloride
Uzarewicz,Dresler
, p. 1921 - 1930 (2007/10/03)
The reactions of selected allylic acetates with methanol, ethanol, n-propyl alcohol, isopropyl alcohol and tert-butyl alcohol in the presence of catalytic amounts of cerium(III) chloride are described. Allylic alkyl ethers, bis-allylic ethers and 1,3-dienes were obtained depending on the structure of the acetates.
The reaction of cyclic allylic alcohols with aliphatic alcohols in the presence of cerium(III) chloride
Uzarewicz,Dresler
, p. 181 - 195 (2007/10/03)
Cyclic secondary and tertiary allylic alcohols react with primary aliphatic alcohols in the presence of cerium(III) chloride heptahydrate to give alkyl allylic ethers. When secondary or tertiary aliphatic alcohols are used 1,3-dienes are obtained from allylic alcohols heaving the 3-methyl-2-en-1-ol moiety (3-8, 13-15).
CLEAVAGE OF (3-CHLORO-2-METHYLENECYCLOALKYL)PALLADIUM CHLORIDE DIMERS: FORMATION OF OLEFINS AND α-METHOXYOLEFINS
Donaldson, William A.
, p. 2901 - 2908 (2007/10/02)
The cleavage of the title compounds (7) in methanolic potassium hydroxide gives mixtures of olefins and α-methoxyolefins in good yields.The ratio of the products is dependent on the size of the carbocyclic ring.The mechanism proposed involves cleavage of 7 to the corresponding allylic chloride (8).Solvolysis of the chloride gives the α-methoxyolefin.Alternatively, oxidative addition of 8 to Pd(O) generates a new ?-allyl complex which affords the olefin product upon subsequent cleavage.
Anti-Markovnikov Addition of Nucleophiles to a Non-conjugated Olefin via Single Electron Transfer Photochemistry
Gassman, Paul G.,Bottorff, Kyle J.
, p. 5449 - 5452 (2007/10/02)
Nucleophilic solvent has been added regiospecifically in an anti-Markovnikov manner to a simple non-conjugated olefin, 1-methylcyclohexene, through single electron transfer induced photochemistry using the 1-cyanonaphthalene - biphenyl pair for achieving photooxidation.
Deamination of N-(6-endo-Methylbicyclohex-6-exo-yl)- and N-(6-endo-Methylbicyclohex-2-en-6-exo-yl)-N-nitrosourea. Attempted Non-photochemical Generation of trans-Cyclohexene Derivatives
Jendralla, Heiner
, p. 3585 - 3596 (2007/10/02)
Decomposition of the stereochemically fixed diazonium ions 12 in alkaline methanol affords only 3-substituted 2-methylcyclohexenes 32-36.The corresponding unsaturated diazonium ions 18 gave the products 37-39.Reactions that have been found when generating
