38586-05-9Relevant academic research and scientific papers
B(C6F5)3 catalyzed direct nucleophilic substitution of benzylic alcohols: an effective method of constructing C-O, C-S and C-C bonds from benzylic alcohols
Meng, Shan-Shui,Wang, Qian,Huang, Gong-Bin,Lin, Li-Rong,Zhao, Jun-Ling,Chan, Albert S. C.
, p. 30946 - 30949 (2018/09/13)
An efficient and general method of nucleophilic substitution of benzylic alcohols catalyzed by non-metallic Lewis acid B(C6F5)3 was developed. The reaction could be carried out under mild conditions and more than 35 exampl
A Sterically Congested α-Cyanoamine as a Cyanating Reagent: Cyanation of Acetals and Orthoesters
Kotani, Shunsuke,Sakamoto, Midori,Osakama, Kazuki,Nakajima, Makoto
supporting information, p. 6606 - 6609 (2015/10/29)
The cyanation of acetals and orthoesters by using a sterically congested α-cyanoamine as a cyanating reagent was investigated. The α-cyanoamine effectively facilitated cyanation in the presence of trichlorosilyl triflate to produce a variety of cyanated adducts in excellent yields. Analysis of the reaction mixture by 1H NMR spectroscopy revealed that trichlorosilyl triflate produced an oxocarbenium cation species as an intermediate.
A novel one-pot synthesis of cyanohydrin alkyl ethers from aldehydes catalyzed by iron(III) chloride
Iwanami, Katsuyuki,Oriyama, Takeshi
, p. 1324 - 1325 (2007/10/03)
A variety of cyanohydrin alkyl ethers were readily prepared from aldehydes with trimethylsilyl cyanide and alkoxy-trimethylsilane under the influence of a catalytic amount of iron(III) chloride in a convenient one-pot procedure.
