38597-97-6Relevant articles and documents
Zinc Barbier reaction of propargyl halides in water
Bieber, Lothar W.,Da Silva, Margarete F.,Da Costa, Rosenildo C.,Silva, Lilia O.S.
, p. 3655 - 3658 (2007/10/03)
The reaction of propargyl halides and carbonyl compounds with zinc powder proceeds in concentrated aqueous salt solutions affording with high selectivity homopropargylic alcohols preparatively useful yields are obtained with aromatic and aliphatic aldehydes. Ketones and 2-hydroxybenzaldehydes react partially. A surface process of two SET is discussed.