27521-80-8Relevant articles and documents
Synthesis and reactivity of metal carbene complexes with heterobiaryl spacer substituents
Lotz, Simon,Crause, Chantelle,Olivier, Andrew J.,Liles, David C.,Goerls, Helmar,Landman, Marile,Bezuidenhout, Daniela I.
, p. 697 - 710 (2009)
Mono- and binuclear Fischer carbene complexes, [M(CO)5{C(OR)Ar- ArX}], X = H, {C(OR)M′(CO)5}; M, M′ = W or Cr; R = Me, Et or (CH2)4OMe; Ar = thiophene, N-methylpyrrole or furan units 1-20, were synthesized. For
Wynberg et al.
, p. 1011 (1971)
N-Heterocarbene Palladium Complexes with Dianisole Backbones: Synthesis, Structure, and Catalysis
Li, Dong-Hui,He, Xu-Xian,Xu, Chang,Huang, Fei-Dong,Liu, Ning,Shen, Dong-Sheng,Liu, Feng-Shou
, p. 2539 - 2552 (2019/06/17)
A series of palladium N-heterocyclic carbenes (NHCs), complexes C1-C5, bearing dianisole backbones and substituted N-aryl moieties have been synthesized and characterized. The electronic effect as well as the steric environment of the NHC ligands has been assessed. The synthesized palladium complexes were applied for Suzuki-Miyaura cross-coupling reactions under aerobic conditions. The relationship between the catalytic structure and catalytic performance was then extensively investigated. Upon optimizing the reaction conditions, the C4 was found to be highly efficient to catalyze the cross-coupling of (hetero)aryl chlorides with (hetero)arylboronic acids at a 0.1 mol % palladium loading.
Palladacycle-catalyzed Suzuki-Miyaura reaction of aryl/heteroaryl halides with MIDA boronates in EtOH/H2O or H2O
Li, Yabo,Wang, Jingran,Wang, Zhiwei,Huang, Mengmeng,Yan, Beiqi,Cui, Xiuling,Wu, Yusheng,Wu, Yangjie
, p. 36262 - 36266 (2014/11/08)
With good to excellent yields, a series of mono- or diheteroaryl compounds were synthesized via the palladacycle-catalyzed Suzuki-Miyaura reaction of various N-methyliminodiacetic acid (MIDA) boronates with aryl/heteroaryl halides in EtOH/H2O or H2O. This journal is the Partner Organisations 2014.
