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Phenol, 2-[(2-pyridinylmethylene)amino]-, also known as 2-(2-pyridylmethyleneamino)phenol or 2-(2-pyridylmethyleneamino)phenol, is an organic compound with the chemical formula C11H10N2O. It is a derivative of phenol, where a 2-pyridylmethyleneamino group is attached to the 2-position of the phenol ring. Phenol, 2-[(2-pyridinylmethylene)amino]- is characterized by its yellow crystalline appearance and is soluble in organic solvents such as ethanol and acetone. It has potential applications in the synthesis of various pharmaceuticals and chemical compounds due to its unique structure and reactivity.

3860-58-0

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3860-58-0 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 3860-58-0 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 3,8,6 and 0 respectively; the second part has 2 digits, 5 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 3860-58:
(6*3)+(5*8)+(4*6)+(3*0)+(2*5)+(1*8)=100
100 % 10 = 0
So 3860-58-0 is a valid CAS Registry Number.

3860-58-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 17, 2017

Revision Date: Aug 17, 2017

1.Identification

1.1 GHS Product identifier

Product name 6-(1H-pyridin-2-ylidenemethylimino)cyclohexa-2,4-dien-1-one

1.2 Other means of identification

Product number -
Other names N-2-pyridylmethylidine-2-hydroxyphenylamine

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:3860-58-0 SDS

3860-58-0Relevant academic research and scientific papers

Nickel(II) complexes with N,N,O-donor Schiff bases. Self-assembly to two-dimensional network via hydrogen bonding

Mukhopadhyay, Abhik,Pal, Samudranil

, p. 737 - 744 (2005)

The syntheses, characterization and crystal structures of two mononuclear nickel(II) complexes are described. Reactions of Ni(O2CCH 3)2·4H2O with the Schiff bases derived from 2-pyridinecarbaldehyde and ortho-am

Grid-corner analogues: Synthesis, characterisation and spectroscopic properties of meridional complexes of tridentate NNO Schiff-base ligands

Stefankiewicz, Artur R.,Wa?esa-Chorab, Monika,Szcze?niak, Hanna B.,Patroniak, Violetta,Kubicki, Maciej,Hnatejko, Zbigniew,Harrowfield, Jack

, p. 178 - 187 (2010)

Reactions of the tridentate Schiff-base ligands HL1, HL2 and HL3 formed from pyridine-2-aldehyde and 2-aminophenol plus two of its methoxycarbonyl derivatives, with AgNO3, [Cu(CH3CN)4]PFsu

Synthesis, Theoretical Study and Catalytic Application of Oxidometal (Mo or V) Complexes: Unexpected Coordination Due to Ligand Rearrangement through Metal-Mediated C-C Bond Formation

Pasayat, Sagarika,B?hme, Michael,Dhaka, Sarita,Dash, Subhashree P.,Majumder, Sudarshana,Maurya, Mannar R.,Plass, Winfried,Kaminsky, Werner,Dinda, Rupam

, p. 1604 - 1618 (2016)

Two novel dioxidomolybdenum(VI) complexes [MoO2L′1] (1) and [MoO2L′2] (2) containing the MoO22+ motif with unexpected coordination motifs due to ligand rearrangement through Mo-mediated int

N,O-Amino-phenolate Mg(II) and Zn(II) Schiff base complexes: Synthesis and application in ring-opening polymerization of ε-caprolactone and lactides

Munzeiwa, Wisdom A.,Nyamori, Vincent O.,Omondi, Bernard

, p. 264 - 274 (2019)

Solventless grinding of 2-aminophenol and the corresponding aldehyde furnished compounds 2-(pyridin-2-ylmethylene)aminophenol (L1), 2-(pyridin-4-ylmethylene)aminophenol (L2), 2-(thiophen-2-ylmethylene)aminophenol (L3) and 2-(furan-2-ylmethylene)aminopheno

Modulating In Vitro Photodynamic Activities of Copper(II) Complexes

Musib, Dulal,Raza, Md Kausar,Kundu, Somashree,Roy, Mithun

, p. 2011 - 2018 (2018)

The photodynamic activities of selected copper(II) complexes [Cu(L1)B]ClO4 (1,2) and [Cu(L2)B]ClO4 (3,4), where L1 = 2-[(pyridin-2-yl)methyleneamino]phenol, L2 = 2-[(pyridin-2-yl)methylenea

A turn-on Schiff-base fluorescence sensor for Fe3 + ion

Chen, Chang-Hung,Hung, Pei-Ju,Wan, Chin-Feng,Wu, An-Tai

, p. 74 - 77 (2013)

We synthesized a novel Schiff-based fluorescent receptor 2, and investigated its binding properties toward various metal ions. The receptor 2 exhibited a blue shift in emission band upon binding with Fe3 +. The receptor 2 exhibited a high assoc

Effects of appended hydroxyl groups and ligand chain length on copper coordination and oxidation activity

Jehdaramarn, Attawit,Pornsuwan, Soraya,Chumsaeng, Phongnarin,Phomphrai, Khamphee,Sangtrirutnugul, Preeyanuch

, p. 654 - 661 (2017/12/28)

Treatment of a series of (imino)pyridine ligands bearing appended hydroxyl groups 2-((pyridin-2-ylmethylene)amino)phenol (Hpyph), 2-((pyridin-2-ylmethylene)amino)ethanol (Hpyet), and 3-((pyridin-2-ylmethylene)amino)propanol (Hpypr) with one equiv. of CuCl2·2H2O afforded the corresponding Cu(ii) complexes in low to moderate yields. The crystal structure of (μ-Cl)2[CuCl(κ2-N,N-Hpyet)]2 reveals a symmetric dinuclear structure with the bidentate N,N-coordination mode of (imino)pyridine with no Cu-OH interaction. On the other hand, the dinuclear Cu(ii) complex of the related propyl ligand Hpypr possesses a significantly different crystal structure involving nucleophilic addition of the hydroxyl group to the aldehyde group of 2-pyridinecarboxaldehyde. The Cu complex/Cu0/TEMPO/Na2CO3 (TEMPO = 2,2,6,6-tetramethylpiperidinyl-1-oxyl) catalyst system generally exhibited good activity for aerobic oxidation of benzyl alcohol to benzaldehyde in H2O at room temperature. The dinuclear Cu(ii) complex (μ-Cl)2[CuCl(κ2-N,N-Hpyet)]2 was demonstrated as an effective catalyst toward aerobic oxidation of various benzyl alcohol derivatives, cinnamyl alcohol, and 2-thiophenemethanol.

Biological properties of heterocyclic pyridinylimines and pyridinylhydrazones

Martins, Francislene J.,Lima, Rebeca Mól,Dos Santos, Juliana Alves,De Almeida Machado, Patrícia,Coimbra, Elaine Soares,Da Silva, Adilson David,Raposo, Nádia Rezende Barbosa

, p. 107 - 114 (2015/11/17)

This work describes the synthesis and biological properties of a series of 2- and 4- pyridinylimines and pyridinylhydrazones. All compounds were evaluated in vitro against two species of Leishmania. The antioxidant activity and the toxic effect against mu

Biological properties of heterocyclic pyridinylimines and pyridinylhydrazones

Martins, Francislene J.,Lima, Rebeca Ml,Dos Santos, Juliana Alves,De Almeida Machado, Patricia,Coimbra, Elaine Soares,Da Silva, Adilson David,Raposo, Ndia Rezende Barbosa

, p. 107 - 114 (2015/12/01)

This work describes the synthesis and biological properties of a series of 2- and 4-pyridinylimines and pyridinylhydrazones. All compounds were evaluated in vitro against two species of Leishmania. The antioxidant activity and the toxic effect against mur

A biomimetic phenol substituent effect on the reaction of a dimethylplatinum(ii) complex with oxygen: Proton coupled electron transfer and multiple proton relay

Moustafa, Mohamed E.,Boyle, Paul D.,Puddephatt, Richard J.

supporting information, p. 10334 - 10336 (2015/06/25)

The complex [PtMe2({κ2-N,N-RNCH-2-C5H4N})] reacts with oxygen in acetone solution to give the platinum(iv) complex [Pt(OH)Me2{κ3-N,N,O-RNH-CH(2-C5H4N)(CHCMeO)}], when

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