38697-07-3Relevant articles and documents
Concurrent Formation of N-H Imines and Carbonyl Compounds by Ruthenium-Catalyzed C-C Bond Cleavage of β-Hydroxy Azides
Lee, Jeong Min,Bae, Dae Young,Park, Jin Yong,Jo, Hwi Yul,Lee, Eunsung,Rhee, Young Ho,Park, Jaiwook
supporting information, p. 4608 - 4613 (2020/06/05)
A commercial cyclopentadienylrutenium dicarbonyl dimer ([CpRu(CO)2]2) efficiently catalyzes the formation of N-H imines and carbonyl compounds simultaneously from β-hydroxy azides via C-C bond cleavage under visible light. Density functional theory calculations for the cleavage reaction support the mechanism involving chelation of alkoxy azide species and liberation of nitrogen as the driving force. The synthetic utility of the reaction was demonstrated by a new amine synthesis promoted by chemoselective allylation of imine and synthesis of isoquinoline.
Reactions of N, N-dichloroalkylamines with solid base as studied by FTIR combined with DFT calculations
Egawa,Ito,Konaka
, p. 337 - 344 (2007/10/03)
Products of vacuum gas-solid reactions of N, N-dichloroalkylamines with KOH have been identified by FTIR spectroscopy and DFT calculations. It has been found that the reactions consist of elimination of two Cl atoms accompanied with migration of an H atom, a ring carbon or a methyl group from the α-carbon to the N atom and unstable imines with a C=N double bond are formed.
Gas-phase reactions. 66. Gas-phase pyrolyses of alkyl azides: experimental evidence for chemical activation.
Bock,H.,Dammel,R.
, p. 5261 (2007/10/07)
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