38730-40-4Relevant academic research and scientific papers
Palladium-Catalyzed Enantioselective Synthesis of 2-Aryl Cyclohex-2-enone Atropisomers: Platform Molecules for the Divergent Synthesis of Axially Chiral Biaryl Compounds
Pan, Chongqing,Zhu, Zixi,Zhang, Mingkai,Gu, Zhenhua
supporting information, p. 4777 - 4781 (2017/04/13)
The palladium-catalyzed asymmetric synthesis of enone-based atropisomers from 2-iodo-3-methylcyclohex-2-enones and aryl boronic acid is reported. BoPhoz-type phosphine–aminophosphine ligands showed superior enantioselectivity over other ligands. These cyc
