38734-05-3

Basic information

• Product Name: 1,6-Cyclodecanedione
• Synonyms: 1,6-Cyclodecanedione
• CAS NO: 38734-05-3
• Molecular Formula: C₁₀H₁₆O₂
• Molecular Weight: 168.2328
• Mol File: 38734-05-3.mol
• Article Data: 16

Chemical Properties

• Boiling Point: 295.9°Cat760mmHg
• Flash Point: 110.4°C
• Appearance: /
• Density: 0.987g/cm³
• Vapor Pressure: 0.00149mmHg at 25°C
• Refractive Index: 1.456
• CAS DataBase Reference: 1,6-Cyclodecanedione(CAS DataBase Reference)
• NIST Chemistry Reference: 1,6-Cyclodecanedione(38734-05-3)
• EPA Substance Registry System: 1,6-Cyclodecanedione(38734-05-3)

Safety Data

• Hazardous Substances Data: 38734-05-3(Hazardous Substances Data)

Usage

Chemical structure

Cyclic ketone with a six-carbon ring and two carbonyl groups attached

Synonyms

1,6-Diketocyclodecane

Applications

Synthesis of various organic compounds
Building block in the production of pharmaceuticals, fragrances, and other fine chemicals

Biological activity

Studied for its potential biological activity and has shown promise as a versatile starting material in organic synthesis

Polymer production

Investigated for its potential use in producing high-performance polymers

Corrosion inhibition

Investigated as a potential corrosion inhibitor

Versatility

Wide range of potential applications in various industries
These properties and specific content provide a comprehensive overview of 1,6-Cyclodecanedione, highlighting its chemical structure, applications, and potential for further research and development in various fields.

InChI:InChI=1/C10H16O2/c11-9-5-1-2-6-10(12)8-4-3-7-9/h1-8H2

Upstream product

• 493-03-8 1,2,3,4,5,6,7,8-octahydro-naphthalene 
• 67-56-1 methanol 
• 57289-63-1 (4ar,8ar)-octahydronaphthalene-4a,8a-diol 
• 546-67-8 lead(IV) tetraacetate 
• 64-19-7 acetic acid 
• 127-08-2 potassium acetate 
• 57601-88-4 3,4:3,4-Dibutano-1,2-dioxetan 
• 28795-95-1 cis-9,10-decalinediol 
• 119-64-2 tetralin 
• 825-51-4 decahydronaphthalen-2-ol 
• 64-17-5 ethanol 
• 412033-28-4 cyclodecane-1,1,6,6-tetrayl tetrahydroperoxide 
• 493-01-6 cis-decalin 
• 22464-22-8 cyclodeca-3,8-diene-1,6-dione bis(ethylene acetal) 

Downstream Products

• 84531-26-0 C₂₂H₂₆Cl₂N₄ 
• 84531-25-9 C₂₂H₂₆N₆O₄ 
• 32453-08-0 Cyclodecan-1,6-diol 
• 32453-08-0 cis-cyclodecane-1,6-diol 
• 7125-60-2 1(7)-bicyclo<5.3.0>decene 
• 62547-99-3 Δ⁴⁽¹⁰⁾-octahydroazulene 
• 107779-51-1 1-methyl-6-(4-nitro-benzoyloxy)-11-oxa-bicyclo[4.4.1]undecane 
• 84531-33-9 Acetic acid 6-acetoxy-1,6-bis-(4-chloro-phenylazo)-cyclodecyl ester 
• 84531-33-9 Acetic acid 6-acetoxy-1,6-bis-(4-chloro-phenylazo)-cyclodecyl ester 
• 84531-34-0 C₂₂H₂₄Cl₂N₄ 
• 84531-31-7 C₂₂H₂₄Cl₂N₄ 
• 84531-32-8 Acetic acid 6-acetoxy-1,6-bis-(4-nitro-phenylazo)-cyclodecyl ester 
• 84531-30-6 C₂₂H₂₄N₆O₄ 
• 84531-27-1 C₂₂H₂₆N₄ 

Relevant articles and documents

PREPARATION AND SPECTROSCOPIC PROPERTIES OF CYCLODECA-1,6-DIYNE

The preparation of cyclodeca-1,6-diyne (1) is reported.The PE results reveal a strong interaction between the in plane ? molecular orbitals of 1.

Sodium Hypochlorite Pentahydrate as a Reagent for the Cleavage of trans-Cyclic Glycols

Sodium hypochlorite pentahydrate (NaOCl·5H2O) can be used toward the efficient glycol cleavage of trans-cyclic glycols, which are generally resistant to this transformation. Interestingly, the reaction of cis-cyclic glycols with NaOCl·5H2O is slower than that observed for the corresponding trans-isomer. This trans selectivity is in sharp contrast to traditional oxidants used for glycol cleavage. Acyclic glycols can also react efficiently with NaOCl·5H2O to form their corresponding carbonyl compounds in high yield.

Aliphatic C-H activation with aluminium trichloride-acetyl chloride: Expanding the scope of the Baddeley reaction for the functionalisation of saturated hydrocarbons

The functionalisation of decalin by means of an "aliphatic Friedel-Crafts" reaction was reported over fifty years ago by Baddeley et al. This protocol is of current relevance in the context of C-H activation and here we demonstrate its applicability to a range of other saturated hydrocarbons. Structural elucidation of the products is described and a mechanistic rationale for their formation is presented. The "aliphatic Friedel-Crafts" procedure allows for production of novel oxygenated building blocks from abundant hydrocarbons and as such can be considered to add significant synthetic value in a single step.

Catalytic oxidation of C-H bonds

The invention provides a catalytic, chemospecific and stereospecific method of oxidizing a wide variety of substrates without unwanted side reactions. Essentially, the method of the instant invention, under relatively mild reaction conditions, catalytically, stereospecifically and chemospecifically inserts oxygen into a hydrocarbon C—H bond. Oxidation (oxygen insertion) at a tertiary C—H bond to form an alcohol (and in some cases a hemiacetal) at the tertiary carbon is favored. The stereochemistry of an oxidized tertiary carbon is preserved. Ketones are formed by oxidizing a secondary C—H bond and ring-cleaved diones are formed by oxidizing cis tertiary CH bonds.