59686-17-8

Upstream product

• 58220-80-7 (2E,6E,10Z)-(S)-14-Isopropenyl-3,7,11-trimethyl-cyclotetradeca-2,6,10-trienone 
• 72623-61-1 (2E,6E,10Z)-14-Isopropenyl-3,7,11-trimethyl-cyclotetradeca-2,6,10-trienone 
• 59664-63-0 (2E,6E,10Z)-(1R,14S)-14-Isopropenyl-3,7,11-trimethyl-cyclotetradeca-2,6,10-trienol 

Downstream Products

• 59664-63-0 (2E,6E,10Z)-(1S,14S)-14-Isopropenyl-3,7,11-trimethyl-cyclotetradeca-2,6,10-trienol 
• 38748-84-4 (–)-(R)-cembrene A 
• 72690-76-7 ((1R,2S,5R)-2-Isopropyl-5-methyl-cyclohexyloxy)-acetic acid (2E,6E,10E)-(1R,14S)-14-isopropenyl-3,7,11-trimethyl-cyclotetradeca-2,6,10-trienyl ester 
• 72638-68-7 ((1S,2R,5S)-2-Isopropyl-5-methyl-cyclohexyloxy)-acetic acid (2E,6E,10E)-(1S,14R)-14-isopropenyl-3,7,11-trimethyl-cyclotetradeca-2,6,10-trienyl ester 

Relevant academic research and scientific papers

PREPARATION OF ENANTIOMERICALLY PURE 1-HYDROXY-NEOCEMBRENES TO DETERMINE THE UNSOLVED ABSOLUTE CONFIGURATION OF CEMBRENOIDS

Cis and trans 1-hydroxy-neocembrenes were prepared in an enantiomerically pure form by reduction of dl-ketone with respective (+)- and (-)-Darvon-LiAlH4 complex followed by purification with the aids of esterification with d- and l-menthoxyacetyl chlorides and (-)-camphanic acid chloride, respectively.Absolute configuration of naturally occurring (+)-mayol and (+)-cembrenene was determined by correlation with enantiomerically pure compounds.