57766-62-8Relevant academic research and scientific papers
Novel Synthesis of (-)-(R)-Cembrene A, Synthesis of (+)-(R)-Cembrenene and (+)-(S)-Cembrene
Farkas, Imre,Pfander, Hanspeter
, p. 1980 - 1985 (2007/10/02)
A novel synthesis of (-)-(R)-cembrene A ((-)-3) was developed using the Sharpless epoxidation for the introduction of the chiral center.Furthermore, the synthesis of (+)-(R)-cembrenene ((+)-4) showed that this cembranoid must have the (R)-configuration and not, as previously reported, the (S)-confguration.Selective hydrogebation of (+)-4 afforded (+)-(S)-cembrene ((+)-5).
SYNTHESIS OF MACROCYCLIC TERPENOIDS BY INTRAMOLECULAR CYCLIZATION VI. SYNTHESIS OF 3Z-CEMBRENE A AND CEMBRENENE
Shimada, Kazuaki,Kodama, Mitsuaki,Ito, Sho
, p. 4275 - 4276 (2007/10/02)
Two 14-membered diterpenes, 3Z-cembrene A and cembrenene, isolated from a termite and a soft coral, respectively, were synthesized by the anion-induced cyclization of geranyl-geranyl phenyl sulfide.
