38814-48-1

Basic information

• Product Name: tricarbonyl(η6-8,8-dimethylheptafulvene)chromium(0)
• Synonyms: tricarbonyl(η6-8,8-dimethylheptafulvene)chromium(0)
• CAS NO: 38814-48-1
• Molecular Weight: 268.232
• Mol File: 38814-48-1.mol

Chemical Properties

• CAS DataBase Reference: tricarbonyl(η6-8,8-dimethylheptafulvene)chromium(0)(CAS DataBase Reference)
• NIST Chemistry Reference: tricarbonyl(η6-8,8-dimethylheptafulvene)chromium(0)(38814-48-1)
• EPA Substance Registry System: tricarbonyl(η6-8,8-dimethylheptafulvene)chromium(0)(38814-48-1)

Safety Data

• Hazardous Substances Data: 38814-48-1(Hazardous Substances Data)

Upstream product

• 96093-48-0 dicarbonyl(2-6:2'-4'-η-[1-(2,3-dimethyl-3-butene-1,2-diyl)-7-isopropylidene-3,5-cycloheptadiene-2-yl])chromium 

Downstream Products

• 89300-34-5 dicarbonyl(1''-5'':3',5',-η-[1-(cyclopentadiendiyl)-1-(7-isopropyliden-1,4-cycloheptadien-3,6-diyl)-1-phenylethane])chromium 
• 89234-41-3 dicarbonyl(1''-5'':3'-5'-η-[(cyclopentadiendiyl)(7-isopropyliden-1,4-cycloheptadien-3,6-diyl)diphenylmethane])chromium 

Relevant articles and documents

PHOTOCHEMISCHE REAKTIONEN VON UEBERGANGSMETALL-OLEFIN-KOMPLEXEN. IX. ADDITIONS-SUBSTITUTIONS-REAKTION VON 2,3-DIMETHYL-1,3-BUTADIEN AN TRICARBONYL(η6-8,8-DIMETHYL-HEPTAFULVEN)CHROM(0)

Under UV irradiation tricarbonyl(η6-8,8-dimethylheptafulvene)chromium(0) (I) reacts with 2,3-dimethyl-1,3-butadiene (II) in an unusual addition-substitution manner.A dicarbonylchromium(0) complex with a η3:5-butenylenecycloheptadienyl chelating ligand (III) is formed in good yield.Treatment of III with CO at 273 K and atmospheric pressure yields the corresponding substituted tricarbonyl(η6-bicycloundeca-2,4,8-triene)chromium(0) complex (IV), which is the formal -cycloadduct of I and II.The structures of III and IV are elucidated by IR, 1H NMR and 13C NMR spectroscopy.