38829-09-3

Upstream product

• 589-87-7 1,4-bromoiodobenzene 
• 32657-89-9 1,3-butadien-2-ylmagnesium chloride 
• 766-96-1 4-bromo-1-ethynylbenzene 
• 74-85-1 ethene 
• 99-90-1 para-bromoacetophenone 
• 1826-67-1 vinyl magnesium bromide 

Downstream Products

• 51431-65-3 1-Bromo-4-(2,2-dichloro-1-vinyl-cyclopropyl)-benzene 
• 51431-71-1 1-Bromo-4-(2,2-dichloro-1-ethyl-cyclopropyl)-benzene 
• 1236124-02-9 C₂₀H₂₇BrN₂O₃ 
• 1236123-86-6 C₂₀H₂₇BrN₂O₃ 
• 1573120-85-0 (E)-3-(4-bromophenyl)-1-phenyl-3-penten-1-one 

Relevant academic research and scientific papers

Synthesis of 2-Substituted 1,3-Butadienes by Cross-coupling Reaction of 2-(1,3-Butadienyl)magnesium Chloride with Alkyl or Aryl Iodides

The cross-coupling reactions of 2-(1,3-butadienyl)magnesium chloride (1) with aryl and alkyl iodides were investigated in the presence of transition metal catalysts.Tetrakis(triphenylphosphine)palladium(0) catalyzes the cross-coupling reactions of 1 with

Diversity-oriented synthesis of biaryl derivatives using cross-enyne metathesis, diels-alder reaction, and suzuki-miyaura cross-coupling as key steps

Biaryl derivatives have been prepared by utilizing cross-enyne metathesis, Diels-Alder reaction followed by aromatization. These biaryl derivatives are further functionalized via Suzuki-Miyaura cross-coupling reaction to generate functionalized terphenyl derivatives. Georg Thieme Verlag Stuttgart - New York.

Enantioselective (Formal) Aza-diels-alder reactions with non-danishefsky-type dienes

Enantioselective (formal) aza-Diels-Alder reactions between acylhydrazones and non-Danishefsky-type dienes have been developed. The reactions are promoted by a simple and economical chiral silicon Lewis acid and are typically conducted at ambient temperature. Both glyoxylate- and aliphatic aldehyde-derived hydrazones may be employed, as may variously substituted dienes, leading to the synthesis of a diverse array of tetrahydropyridines with good to excellent levels of enantioselectivity.