38850-27-0

Upstream product

• 65-85-0 benzoic acid 
• 455-32-3 benzoyl fluoride 
• 1070-89-9 sodium hexamethyldisilazane 
• 618-38-2 benzoyl iodide 
• 1357556-77-4 N-triethylgermyl-N,N-bis(trimethylsilyl)amine 
• 268208-86-2 N-triethylstannyl-N,N-bis(trimethylsilyl)amine 
• 1586-73-8 tris(trimethylsilyl)amine 
• 75-79-6 Methyltrichlorosilane 
• 22180-78-5 N,N-dichloro-benzamide 

Downstream Products

• 71877-41-3 N-phenylsulfonyl-N'-benzoylselenium diimide 
• 71877-44-6 C₁₄H₁₂N₂O₃SSe 
• 20043-21-4 N-Benzoylthionylimide 
• 61945-93-5 N,N'-dibenzoylselenium diimide 
• 25922-45-6 Triphenylarsin N-benzoylimin 
• 87786-72-9 2,6-diphenyl-4-phenylsulfonylimino-5,6-dihydro-4,1,3-selenaoxazine 
• 87786-79-6 4-Chloro-N-[2,6-diphenyl-5,6-dihydro-4λ⁴-[1,4,3]oxaselenazin-(4Z)-ylidene]-benzenesulfonamide 
• 70890-23-2 2,6-diphenyl-4,4-dichloro-5,6-dihydro-4,1,3-selenaoxazine 
• 95477-24-0 (2-phenyl-2-benzoyloxyethyl)methoxyselenium dichloride 
• 70890-24-3 C₇H₅Cl₂NOSe 
• 87786-82-1 N-p-chlorophenylsulfonyl-N'-benzoylselenium diimide 
• 61706-76-1 2-trimethylsiloxy-4,5-benzo-1,3,2-dioxaphospholane 
• 100-47-0 benzonitrile 

Relevant academic research and scientific papers

Direct amidation of acid fluorides using germanium amides

Amide functional groups are an essential linkage that are found in peptides, proteins, and pharmaceuticals and new methods are constantly being sought for their formation. Here, a new method for their preparation is presented where germanium amides Ph3GeNR2convert acid fluorides directly to amides. These germanium amides serve to abstract the fluorine atom of the acid fluoride and transfer their amide group -NR2to the carbonyl carbon, and so function as amidation reagents.